METALLURGICAL TECHNOLOGIES
RESOURCE SAVING IN FERROUS METALLURGY
The further development of the Russian coal industry, especially in the regions of Siberia and the Far East, in line with the Energy Strategy, predetermines the need to address the problem of utilization of ash and slag wastes in newly implemented projects. The total amount of ash and slag in the ash dumps in Russia is more than 1.5 billion tons, and the area occupied by fly ash and slag wastes (FASW) is more than 220 km2. At the same time, the degree of FASW use does not exceed 10 %. It is shown that the main solutions for the recycling of the industrial solid waste generated by thermal power plants are their use in the production of building materials, road construction, or the complex processing of FASW with the extraction of metals and the production of building mate rials either. Some fly ash can be used in agriculture. The physicochemical properties of fly ash and slag wastes and, accordingly, the directions of their use, as well as the choice of technology, are determined by the mineral part of the fossil coals and the way they are burned. To use fly ash in the construction industry, it is necessary to transfer the ash removal system to the dry method, accompanied, on the one hand, by a large volume of capital investments in equipment and facilities for storage, classification, crushing and grinding, the transfer of new physical and chemical properties to fly ash and slag waste, and on the other side, an increase in organizational and transport barriers. Examples of proposed technologies for utilization of ash and slag wastes in the form of metal recovery and production of building materials are given. To obtain iron-containing concentrates, one-stage magnetic separation is used, but the quality of the concentrate does not meet modern requirements. The most technologically effective for the extraction of metals from ash and slag wastes are technologies based on flotation methods. At the same time, it follows from the provided data that their application can be limited to economic, organizational factors and the emergence of new environmental risks. The conclusion is made on the possibility of using the above technologies for existing coal-fired power plants only with state support.
MATERIAL SCIENCE
The creation of new structural materials for cladding tubes of fast neutron reactors is an urgent task of modern nuclear power engineering. A three-layer radiation-resistant and corrosion-resistant material based on vanadium alloy and stainless steel, intended for work under extreme conditions (high temperatures, radiation and aggressive environment) of operation of fast neutron reactor cladding tubes has been developed in recent years. The most important aspect determining the operability of this material during operation is the quality of the joining of different materials layers among themselves, determined by the modes of thermomechanical treatment. The effect of the annealing on the chemical composition, structure, and fracture resistance of the “steel/vanadium alloy” interface in the steel/vanadium alloy/steel three-layer tube, obtained by hot co-extrusion of three-layer tube billet at 1100 °C was studied. The 20Kh13 (AISI 420 type) steel for the outer layers and V – 4Ti – 4Cr vanadium alloy for the core were used as the components of the tube. The structure and chemical composition in the layer joining zone were studied using the optical microscopy and electron microscopy with X-ray microspectral analysis. The fracture resistance of the “steel/vanadium alloy” interface was evaluated by a compression test of a three-layer ring sample with notch using an acoustic emission (AE) measurement. It is shown that after co-extrusion a “transition” area of diffusion interaction having a variable chemical composition with a width of 10–15 μm is formed between vanadium alloy and steel, which represents the continuous series of solid solutions, without precipitation of brittle phases, providing a strong bonding between vanadium alloy and steel in the three-layer material. No voids, delaminations or defects
were detected at the “steel/vanadium alloy” interface. However, a crack is formed in the steel layer during the compression tests of the notched semi-ring three-layer samples after hot co-extrusion. Annealing favorably influences the formation of the “transition” area due to the increase in the width of the diffusion interaction area. No cracks or delaminations at the boundary between steel and vanadium layers were observed in the three-layer tube samples after annealing, and the three-layer material behaves like a monolith material during testing.
Using transmission electron microscopy methods at various distances from the rolling surface along the central axis, changes in structure, phase composition, and defective substructure of the head of differentially hardened rails were studied after passed tonnage of 691.8 million tons of gross weight. It is confirmed that prolonged operation of rails is accompanied by two simultaneous processes of transformation of structure and phase composition of plate-pearlite colonies: cutting of cementite plates and dissolution of cementite plates. The first process is carried out by mechanism of cutting carbide particles and removing their fragments, accompanied only by change in their linear dimensions and morphology. The second process of dest ruction of the cementite plates of perlite colonies is carried out by leaving carbon atoms from crystalline lattice of cementite on dislocation, as a result of which phase transformation of rails metal is possible. This is due to a noticeable relaxation of mean energy of carbon atom s binding to dislocations (0.6 eV) and to iron atoms in cementite lattice (0.4 eV). The stages of transformation of cementite plates are
considered: enveloping the plates with sliding dislocations and then splitting them into weakly oriented fragments; penetration of sliding dislocations from ferrite lattice into lattice of cementite; dissolution of cementite and formation of nanoscale particles. The presence of nanosized cementite particles in ferrite matrix is noted due to their removal during dislocation slide. Using expressions of modern physical materials science and X-ray diffraction analysis, influence of content of carbon atoms on structural elements of rail steel was estimated. It is shown that prolonged operation of rails is accompanied by a significant redistribution of carbon atoms in surface layer. In the initial state, the main quantity of carbon atoms is concentrated in cementite particles, and after a long operation of rails, along with cementite particles, carbon is located in defects of crystal structure of steel (dislocation, grain boundaries and subgrains), and in the surface layer of steel atoms carbon is also found in crystal lattice based on α-iron.
PHYSICO-CHEMICAL BASICS OF METALLURGICAL PROCESSES
INNOVATIONS IN METALLURGICAL INDUSTRIAL AND LABORATORY EQUIPMENT, TECHNOLOGIES AND MATERIALS
INFORMATION TECHNOLOGIES AND AUTOMATIC CONTROL IN FERROUS METALLURGY
Planning of pilot testing is among important problems of creation of Enterprise resource planning. Pilot (experimental) projects are intended for testing of the main functions of the created system by limited number of “advanced” users. A key task when planning pilot testing is determination of its volume. If the volume of the pilot project is small, then essentially important functions of system can be not checked, and the probability of detection of essential mistakes at full introduction will be high. If the volume is big, then amount of works on implementation of the pilot project considerably increases, and there will be no necessary speed and flexibility of testing of the main functions, because of which pilot testing is organized, and its efficiency will be close to efficiency of full introduction. The article describes mathematical problem definition of pilot testing scoping which relies on results of the solution of formation problems of a portfolio of IT services and creation scheduling of Enterprise resource planning of the large metallurgical company. The solutions for the considered task are sets of the services and communications which are subject to check between them satisfying to the set restriction for volume of the resources allocated for testing realization, and delivering an optimum to the set criterion. The procedure of the task solution is based on network programming method which relies on structural and similar network representation of criterion and restrictions. The procedure and an example of the solution of the studied task in which separate estimated tasks are solved by method of dichotomizing programming are shown. The received approximate solutions of an objective can be improved by means of the solution of a dual problem of network programming. For the purpose of finding of initial task global optimum, the method of branches and borders can be used in which the criterions of function of the found approximate solutions are applied as border values. The considered task can be generalized for preferences of the consumers of IT service concerning need of check of services various communications. These preferences can be considered by introduction of “scales” of the corresponding communications. The general scheme of the solution of a task at the same time doesn’t change.
SHORT REPORTS
ISSN 2410-2091 (Online)