METALLURGICAL TECHNOLOGIES
ECOLOGY AND RATIONAL USE OF NATURAL RESOURCES
The problem of reducing emissions of sulfur dioxide from the flue gases of coal-fired TPPs is highly relevant for domestic energy in connection with the annual increase in coal production. This article analyzes statistical data in the field of coal mining, describes the current state in the field of gas purification and ash collection in the mining and metallurgical industry of the Russian Federation. To regulate pollutant emissions by stationary sources in Russia, a system of maximum permissible and temporarily agreed emissions (MPE and ENV) was introduced. The country takes part in international programs aimed at protecting the environment from the harmful effects of human activity. Despite the general dynamics of reducing air pollution in the Russian Federation, emissions from mining and metallurgical enterprises only increase. This is due to deficiencies in the technical condition and operation of dust and gas cleaning equipment at electric power enterprises. The main ones are the moral and physical deterioration of the equipment fleet, the need for reconstruction and modernization of devices. The average degree of flue gas cleaning from ash at Russian TPPs is 95.5 %, which is noticeably less than abroad. Efficiency of the gas treatment plants used does not meet modern environmental requirements. The flue gases at our TPPs are not cleaned from sulfur and nitrogen oxides; there are practically no devices for continuous monitoring of TPP emissions. The article provides the rationale for the transition of enterprises to the best available technologies (BAT) in the field of gas purification. The use of a gas conditioning system allows 30 – 40 % reduction in the amount of funds spent on the construction of electrostatic filters. In recent years, in connection with the advent of new technologies for burning coal, filters for the purification of hot gases made of ceramic materials have been created. We have analyzed the state of gas purification and ash collection in the mining and metallurgical industry of the Russian Federation and its impact on the atmosphere. An assessment of the current state of gas purification equipment at the enterprises was carried out.
MATERIAL SCIENCE
To predict the chemical composition of heat-resistant high-chromium steels with ferritic-martensitic structure (HFMS) (with the number of alloying elements up to 10 and the same number of parameters of production and heat treatment technology), a mathematical model is needed. In this work, I searched for the dependences of the yield strength and ultimate strength of HFMS on the content of alloying elements and test temperature without analyzing technological factors due to their uniformity. Analysis of the samples from ten steel grades was carried out on the basis of the experimental data including 63 tensile tests at 20 – 720 °С. Regression multiplicative dependencies are proposed to take into account exponential and power-law form through the corresponding factors: solid solution and dispersion hardening, total temperature softening of the steel, carbon content, total molybdenum and tungsten content, and strengthening effect of manganese. Estimates of the effect of nitrogen and silicon on the predicted strength characteristics have shown that a factor that takes into account the effect of nitrogen improves the model and is necessary in the general formula, and introduction of a factor that takes into account silicon content, worsens the model. Introduction of a silicon factor in the formula may be necessary in analysis of steels with high silicon content (type EP-823). The experimental fact of a close relationship between yield strengths and tensile strengths for the studied HFMS steels made it possible to use for the yield strength the form of equation and forecast for the ultimate strength, which differs only by coefficients in variables. Deviation of the calculated model yield strengths and tensile strengths from experimental is 13 – 18 %. An example of analysis of the yield strength behavior of steels with experimental chemical compositions is given. It is shown that the dependences found for the yield strength and tensile strength are stable with respect to the increase of experimental data matrix: with an increase in the number of experiments from 94 and higher, the coefficient of variation V monotonously decreases up to a maximum array size of 299 experiments.
Influence of the modes of manual electric arc surfacing of coatings with T-590 electrodes on low-alloy steel 09G2S on their structure and hardness was investigated. It is shown that the pulsed arc surfacing of coatings by electrodes forms a fine-dendritic structure of the deposited metal. Microstructure of the heat-affected zone after surfacing consists of several sections: the overheating zone with a widmanstett structure and the normalization zone with a characteristic fine-grained ferrite-perlite structure. In the initial state, the base metal (steel 09G2S) has a hardness of ~2500 MPa. The hardness of the deposited coating material due to strong mixing with the steel metal is ~ 2700 – 3000 MPa, and of thermal impact zone: 2100 – 2300 MPa. When applying the coating on DC mode, heating temperature of the surfacing bath is higher; this, as a consequence, causes grain growth. When coating on pulse modes, a structure with smaller component sizes is formed by directed low-frequency high-energy impact of the electric arc on the formed metal and due to the constant reciprocating motion of the melt with the frequency of current modulation. It was established that the application of the pulse-arc surfacing method allows preserving the previously formed hardening phases in the deposited coatings.
INFORMATION TECHNOLOGIES AND AUTOMATIC CONTROL IN FERROUS METALLURGY
A mathematical description of the material thermal diffusivity aт in a semi-bounded body is proposed with a relatively simple algorithm for its numerical and analytical by solving the inverse problem of thermal conductivity. To solve the problem, it is necessary to obtain the temperature values of the unbounded plate as a result of a thermophysical experiment. A plate can be conditionally considered as a semi-bounded body as long as the Fourier number Fo ≤ Foк (Foк ≈ 0.04–0.06). It is assumed that the temperature distribution over cross-section of the heated layer of the plate R is sufficiently described by a power function whose exponent depends linearly on the Fourier number. A simple algebraic expression is obtained for calculating aт in the time interval ∆τ from the dynamics of temperature change T(Rп , τ) of a plate surface with thickness Rп heated under boundary conditions of the second kind. Temperature of the second surface of the plate T(0, τ) is used only to determine the time of the end of experiment τк. The moment of time τк, in which the temperature perturbation reaches the adiabatic surface x = 0, can be set by the condition T(Rп , τк) – T(0, τ = 0) = 0,1 K. The method of approximate calculation of dynamics of changes in depth of the heated layer R by the values of Rп , τк , and τ is proposed. Calculation of a т for the time interval ∆τ is reduced to an iterative solution of a system of three algebraic equations by matching the Fourier number, for example, using a standard Microsoft Excel procedure. Estimation of the accuracy of a т calculation was made by the test (initial) temperature field of the refractory plate with the thickness Rп = 0.05 m, calculated by the finite difference method under the initial condition T(x, τ = 0) = 300 (0 ≤ x ≤ Rп) at radiation-convective heating. The heating time was 260 s. Calculation of aт, i was performed for 10 time moments τi + 1 = τi + Δτ, τ = 26 s. Average mass temperature of the heated layer for the whole time was T = 302 K. The arithmetic-mean absolute deviation of aт(T = 302 K) from the initial value at the same temperature was 2.8 %. Application of the method will simplify the conduct and processing of experiments to determine the thermal diffusivity of materials.
SHORT REPORTS
ISSN 2410-2091 (Online)