METALLURGICAL TECHNOLOGIES
The article presents the achievements of the Ural scientific school of scientists and metallurgists-heating engineers in improving a wide spectrum of metallurgical technologies determined on a scientific basis of the creative union of two sciences – physics and computer science. In recent years, mathematical modeling in combination with physical significantly reduce the time and scope of the search for optimal solutions and thereby provide more reliable design and commissioning of thermal regimes of established technologies and equipment. Moderni zation of sintering machines was carried out by introduction of automatic control systems of thermal and gas-dynamic processes and by equipping them by the ignition furnaces of new type. These activities with the intensification of heat-mass transfer processes have improved the feasibility and environmental performance of the sinter plants in Russia and abroad. Technological and thermo-physical solutions du ring the pellets firing are associated with organization of the transfer system of gas flows and reconstruction of gas duct system. As a result of reconstruction, the productivity of machines increased by 10 – 17 %, the specific fuel consumption decreased by 8 – 15 % and the discharge of gases after their treatment decreased by 50 – 58 %. Such reconstruction was made for firing machines in Russia, Brazil, Iran. In recent years, the software has been developed for the solution of complex problems in blast furnace production. It was introduced into commercial operation at the largest metallurgical enterprise in Russia – JSC “MMK”. New Cowper blast heaters for blast furnaces are able to provide heating up to 1300 °C or more by the heating of blast furnace gas and air used for heating of Cowper blast heaters at failure from supplements of natural gas. The problem of processing of metallurgical liquid slag is solved by the creation at factories of ferrous metallurgy of Russia, Ukraine, India and China of units, which are capable to provide high productivity rate of slag discharge from 3 to 15 t/ min and by annual volumes of granular slag production – from 0.66 to 2.0 million tons. The installation of the company “Norilsk Nickel” also works successfully. The improvement of thermal modes and equipment of heating furnaces and installations for various purposes is based on mathematical modeling of thermophysical processes, the basis of which is the created dynamic zonal-node method of modeling radiative and complex heat transfer. This method is successfully developing. In recent years, new designs of furnaces are developed, hundreds of furnaces were upgraded. The organization of thermal modes of their operation has led to a significant reduction in specific fuel consumption, improving the quality of metal heating and during heat treatment – the quality of the finished product.
The present article demonstrates the results of experimental and calculated researches of the rapid (gradient) heating of the working layer of the cold working roll barrel in the unit, consisting of a chamber furnace with special design and a spraying unit, located under the furnace in special pit and able to move up for rapid cooling of the working roll layer. In the process of the roll heating its barrel and some parts of the necks are located within the working chamber area while the other (external) parts of the necks are situated outside the heating chamber and rest upon the drive rollers, which are designed to ensure rotation of the roll barrel in the course of its heating and subsequent cooling. Therefore, it is necessary to ensure hardening only of the working roll layer that is why the neck parts located inside the furnace are equipped with special heat-insulated inserts to prevent their hardening. The experimental rolls are equipped with the thermocouples to measure temperature both in different points of their surface and in the depth of their barrel and necks with the aim to develop the various roll heat treatment conditions. A process of heat treatment included rigid requirements concerning smoothness of the roll barrel surface heating at very close limits for under-heating zones in the extreme sections near surface end faces. Besides, it was necessary to ensure low temperature of the necks located within the working furnace area. The experimental researches of the temperature fields under different conditions of the rapid roll heating allowed us to reach a high speed of the roll heating and cooling and, respectively, the required structure of the working roll barrel layer. At the same time, in the process of the experimental researches and calculations of the temperature fields according to the specially developed program, the authors have revealed intensive heat leak via external open neck parts under the existing conditions of heating gas input and output and roll location with the necks being, par tially, beyond the heating chamber. The above-mentioned researches allowed revealing also a sufficient (as compared with the admissible one) non-uniformity of the temperature field of the barrel surface in the end zones of the roll being heated. It was also determined in the course of the experimental researches that change of the external heat exchange conditions between the working furnace area and roll surface does not eliminate non-uniformity of the temperature field in the end surface sections. A method of sufficient non-uniformity decrease of heating of the end roll barrel sections has been offered and executed calculations and analysis of the temperature fields have confirmed the reality of its application.
Carbon footprint is the mass of carbon formed in the full cycle of production of one or another kind of product. This carbon is included in greenhouse gases. Carbon monoxide and greenhouse gases (methane and carbon dioxide) are generated at the production of iron and steel. Methane and carbon monoxide burn up to carbon dioxide by the realization of secondary energy resources. Therefore, the carbon footprint at the production of iron and steel is determined by weight of formed carbon dioxide. As the results of analysis of the production processes of iron and steel it was revealed that the tandem of blast furnace with electric arc furnace is characterized by a lower value of integrated through emissions of CO2 than the tandem of blast furnace with an oxygen converter. It is proposed to process the cast iron, made by one blast furnace, at the same time in the oxygen converter and in one or more electric arc furnaces. Moreover in the electric arc furnace is loaded 30 % of iron which are produced in blast furnace, and the remaining 70 % are complemented by metal scrap. In the oxygen converter the part of cast iron (75 – 85 %) is loaded, which are remained after loading in the arc furnace. The converter is applied by the metal scrap for full loading. Calculations of through emission of carbon dioxide for different triads of these units are made. The simultaneous use of oxygen converter with electric arc furnaces for cast iron smelting obtained from one blast furnace helps to reduce confidently the emission of carbon dioxide to 20 % as it follows from the calculations. This suggests that this triad of used units conforms to green technology. Example of the use of marked triad is for a full load of the converter is applied to metal scrap. the calculations through emissions of carbon dioxide for different triads of these units. From these calculations it follows that the simultaneous use of oxygen converters from electric arc furnaces for smelting iron, obtained from one blast furnace, it helps to reduce the emission of carbon dioxide to 20 %. This suggests that this triad used units conforms to green technology. An example of using the noted triad is the Magnitogorsk Iron and Steel Works, which, in addition to the oxygen converter, uses electric arc furnaces for smelting steel using electric power produced by the enterprise by burning fuel secondary energy resources from aggregates in which fuel is burnt. This practice can be recommended for a number of other metallurgical enterprises.
Natural gas can be additionally used to reduce coke consumption in a shaft furnace of cupola type with an open or closed furnace top. Its burning is typically made in the external hearths installed around the perimeter of the furnace shell. Depending on design, the burners provide a partial or complete pre-mixing of gas and air at air flow rate of 1.2 to 1.5. Further, the combustion gas is fed directly to a charge layer. When implementing this method, the coke consumption was 8 – 9 % of furnace charge and fuel gas consumption was 30 – 40 m3/t of melt. For these conditions, there were observed a slight increase in the temperature of the melt (10 – 20 °C) and productivity growth of 15 – 20 % while reducing the amount of harmful gaseous emissions by 20 – 25 % (mostly of CO). In the work of the cupola, periodic disruptions of the gas-dynamical regime were observed accompanied by the suspension of the charge material layer, as well as cooling of the resulting melt, an increase in chemical underburn and deterioration of service conditions of the lining materials. When using the layered method for the gas mixture combustion, it is fed into the heated layer of bulk mate rials with the air flow rate not below 2.5 – 3.0 with formation of a hightemperature zone of 1350 – 1380 °С and the width of 60 – 70 mm, able to move through the layer at a speed of 15 – 20 mm/min. To implement it in the thick ventilated layer it is necessary to ensure uniform mixing of gas and air, required gas-dynamic conditions and formation of set “gas-air” ratio in the air flow rate more than 2.5 and 3.0. When supplying the cold gas-air mixture in a layer of shaft furnaces by tuyeres, the combustion zone divides the whole layer into two stages: initial and final. The high temperature level of combustion zone provides substantial cooling rate of the materials at the stage of gas-air mixture ignition, which prevents it from fire in free upperlayer space. The absence of direct contact of high temperatures zone with a unit working space increases the reliability and efficiency of this process (no heat losses). The use of the layered method of natural gas burning to heat the cast iron cupola increase the productivity of the melting unit from 10 to 13.6 t/h, or 36 % while reducing specific consumption of coke for 80 kg/t or 33.3 %, decrease in the total consumption of heat for the process by 25 kW, or 18.78 % and heat losses in the exhaust
gases by 25.32 kW, or 16.2 %. The overall thermal efficiency of the unit increased from 35.58 to 42.26 % or by 15.81 %.
INNOVATIONS IN METALLURGICAL INDUSTRIAL AND LABORATORY EQUIPMENT, TECHNOLOGIES AND MATERIALS
Modern regenerative burners for heating and thermal furnaces have rather larger sizes and small heat exchange period time that is connected with a low thermal capacity of the refractory materials applied to production of a nozzle. Considerable decrease in the sizes of nozzle and increase in heat exchange period time can be reached by using the hidden warmth of metals melting, which can be placed in the closed thin-walled reservoirs. In addition, the paper propose section design and a heat exchange unit enable to solve the problem of reducing the size of regenerative unit and increase the time of the swap, compared to existing regenerators that are used for air heating in regenerative burners. The proposed design can be used to create regenerative burners, a new class of highly effective, high temperature air preheating, and considerable time of swap. Such reservoirs, in which temperature of metal melting is equal, are packed in the sections. The next sections’ melting temperature differs approximately by 100 °C. It allows to maintain the fixed section temperature, which is equal the temperature of metal melting in this section, and removing from its surface or giving it, by products of combustion, warmth, which sets out in case of crystallization or is absorbed when metal kernel melts. Calculation of the swap time and the metal mass in one section, based on the joint solution of equations of heat balance and heat transfer between the heated air and the surface of tanks, allows to determine the overall dimensions of each section, filled with melting or crystallizing metal and its heat exchange surface. Fusible kernel mass, sizes of section and heat exchange period time calculations for regenerative block consisting of ten sections with a fusible kernel is given in this work. Calculation proves a possibility of decrease in dimensions of a regenerative nozzle for a 200 kW burner, and increase in heat exchange period time, while air heating temperature remains constant. The technical solution can be used in a thin-walled container in which are placed the metals with different heat of fusion. Large size regenerative burners hamper their use in heating and thermal furnaces, and fast parecidos leads to a decrease in period of operation of the changeover valve.
The design of the air cooling device for the furnace fan’s shaft of rod type of three standard sizes is proposed. During the experiments at the experimental stand, the convective heat transfer from the surface of these devices to the environment at a different shaft rotation frequency was obtained critically. It was established that in the range of variation of the relative length of the rods from 3.3 to 6.1, a regime close to the self-similar mode takes place, where the heat transfer from their surface can be described by a universal dependence. In the range of variation of the relative length of the rods from 6.1 to 8.6, the experimental data are generalized in the form of a power law with a proportionality coefficient that depends on the ratio of the shaft diameter to the outer diameter of the device. The least coefficient of heat transfer from the external surface was found in ST-346 with the largest outside diameter and, correspondingly, the longest rods, which is apparently due to the fact that in the process of heat transfer from the shaft to the environment, the limiting heat exchange section is the heat supply by heat conduction along of the rods axis. The highest heat transfer coefficient under comparable conditions is observed in ST-286 with medium rods, where the heat supply is more balanced by thermal conductivity along the rods and its removal from their external surfaces by convection to the environment. When comparing the data obtained with CT-286 and CT-220, it was found that at the same shaft rotation frequency, the heat transfer coefficient over the surface of ST-286 is about 15–20 %, which is associated with a decrease in intensity of air blowing of shortened rods of ST-220 due to the decrease in their average linear speed of movement along the circumference. From the analysis of the obtained results, it follows that the most effective in comparable conditions is the device with a maximum diameter of 346 mm, where the dissipated thermal power in the steady state is 1.1 times higher than that of the device with a diameter of 286 mm and 2.0 times greater than for devices with a diameter of 220 mm. The obtained materials can be used in the design of heating and thermal furnaces using forced coolant circulation.
PHYSICO-CHEMICAL BASICS OF METALLURGICAL PROCESSES
Lisakovsk deposit of brown iron ore (Kostanay region, Kazakhstan) is developed by the open method, which provides cheaper ore mining. At the LF LLP “Orken”, the ore is enriched in a gravitymagnetic process to produce a gravitational-magnetic concentrate containing 48 to 49 % of Fe, 10 to 12 % of SiO2 , 4.5 to 5.5 % of Al2O3 and 0.7–0.9 % of P. The product is supplied to the agglomeration in JSC “Arcelor Mittal Temirtau” (Temirtau, Kazakhstan). Because of the increased content of phosphorus in the gravitational-magnetic concentrate, the demand for it is limited. Lysakovsk concentrate contains a significant amount of hydrated moisture (up to 12 %). Most of the moisture is in the form of iron hydrates and decomposes at a moderate temperature of 320–350 °C. The other part, apparently, is associated with a phosphorus-containing component decomposing at elevated temperature. In this process, oxidative firing results in the formation of free phosphorus oxide. Studies on decompounding a hydrated phosphorous-containing component in Lisakovsk iron ore concentrate were undertaken to determine kinetics of the process. Removal of phosphorus from the iron ore concentrate during preparation for metallurgical processing is possible after high-temperature oxidizing roasting of the material and subsequent sulphuric acid leaching. Phosphorus is not leached from the original concentrate by hydrometallurgical method. Using high temperature, it is necessary to break the chemical bond and transfer phosphorous to a free oxide. Complete decompounding of the hydrated phosphorous-containing component at roasting affects the quality of subsequent sulphuric acid treatment of the roasted product. High-temperature hydrate moisture is exuded from Lisakovsk concentrate step-by-step. The rate of high-temperature dehydration de creases with the rise of calcination temperature, which is explained by slow water vapour diffusion through the layer of material that becomes packed at the temperature rise.
INFORMATION TECHNOLOGIES AND AUTOMATIC CONTROL IN FERROUS METALLURGY
A feature of the smelting of copper-bearing ores in the Vanyukov furnace is the formation of liquid products in the form of slag and matte melts, which, as a rule, merge into separate containers (mixer furnaces), where it is necessary to maintain the desired temperature. The mixer oven is a cylindrical container lined inside, closed from both sides by end bottoms, on the one hand a burner is installed to heat and maintain the temperature inside the container, on the other hand, a filler neck is placed.Automated burner devices GPM-3,6 were developed, manufactured and put into operation in slag and matte holding furnaces at the copper-smelting plant of Almalyk Mi ning and Metallurgical Complex (Republic of Uzbekistan). The burner devices are designed for heating holding furnaces up to the operating temperatures of 1250 – 1275 °C and 1110 – 1150 °C respectively and maintaining the temperature of liquid melt poured in the mixer at the preset level at any technological operations. The automated system provides reliable and safe operation of the burner devices, including cold ignition, operation within the preset temperature ranges by regulation of heat loads and shutoffs, among other things in case of emergency. Simultaneously, full information is transferred and exchanged with the central controller of the Automated Control System of Vanyukov Furnace through Profibus DP. The developed burner devices fully comply with the requirements of the Technical Regulations of the Customs Union TR TC 010/2011 On Safety of Machines and Equipment and with the norms and rules of metallurgical production. For the gas supply of burners, a special gas ramp was developed, which is a compact (separate) section of the gas pipeline with all the necessary gas equipment for operation of the main and pilot burners, both in manual control mode and in automatic mode. The gas train includes a gas safety system. The presence of such a ramp ensures regulation of the gas pressure to the parameters required for the operation of the main burner, smooth regulation of fuel consumption within the stable operation of the burner, technological accounting of gas consumption for mixer heating and safe operation of the pilot and main burners. For air supply of the burner device, an air ramp was also designed, which is a compact section of the air pipe with shut-off and control valves installed on it. The composition of the air ramp includes a swivel assembly that allows the mixer to rotate to a certain angle for draining the melt without disconnecting the burner air duct.
Experience shows that the creation and successful introduction of modern automated information systems into the practice of metallurgical enterprises largely depends on the technologies used to develop and to select the tools for their software implementation. The article briefly reflects the main technologies and software used to create software for information modeling systems to solve technological problems in metallurgy. The basis is the use of a flexible development methodology – the Agile method, which focuses on the use of iterative develop ment, the dynamic formation of user requirements, and the provision of their implementation as a result of constant interaction within working groups consisting of specialists of various profiles (users, analysts, programmers, testers). Iteration is a relatively short development time (usually a month), after which the users are provided with the next tested version of the software product with new functional properties. The list of realized functional properties is priority for users and is formed from the general list of requirements before the beginning of each itera tion. During each iteration, the following processes are sequentially performed: checking the correctness of the calculation algorithm (if necessary, entering new calculated indicators); functional modeling of the system; improvement of the structure of the subsystem; conceptual modeling of the database, generation of the database model; loading test data into the database; creation of functional diagrams of mathematical library; implementation of client software subsystems; testing and debugging of software; development of reference documentation. Managing individual tasks and monitoring the progress of their implementation in the course of collective software development are carried out on the basis of the Atlassian JIRA system. Code storage and versioning of software are performed in a remote repository on the Atlasian Bitbucket platform. The use of modern technologies, tools and techniques for developing software products makes it possible to create functional, reliable, easy-to-use, followed, integrated systems with minimal risks and at acceptable times.
ISSN 2410-2091 (Online)