METALLURGICAL TECHNOLOGIES
Using the method of electronic microanalysis, it has been established that in magnetite ores magnetite crystals, depending on the temperature-time conditions of natural ore formation, have different microstructure. So in the composition of sedimentary-metamorphic ferruginous quartzites and magmatic skarns, magnetite crystals have a homogeneous structure and are close in composition to stoichio metry. In the Kovdor deposit, magnetite crystals have a heterogeneous structure, in the matrix of crystals of which the isomorphic impurities of Al, Mg, Ti, etc. exist as separate spinel microphases. When the crystals of Kovdor magnetite are restored under conditions close to agglomeration, it is established that in the process of agglomeration, crystals of a heterogeneous structure are destroyed with the formation of two ore phases: solid solutions of magnetite and wustite that do not participate in liquid-phase hardening of agglomerates. At the final stage of production of fluxed agglomerates, calcium silicate bonds (melilitic composition) with low strength properties are formed in the composition of the finished product at the melt site. In accordance with the results of the present study, the physical and chemical processes of hardening of fluxed agglomerates using magmatic ores of different genesis it is suggested, when buying iron ore deposits, to pay attention not only to the content of iron oxides and silicon in the ores, but also on the structural features of crystals of magnetite itself. At the same time, there are a number of magmatic ore occurrences in which the magnetite crystals have a heterogeneous structure.
RESOURCE SAVING IN FERROUS METALLURGY
The article describes the development carried out within framework of the state program, which provides development of industrial enterprises, including enterprises of metallurgical cycle. Such enterprises are complex plants and associations of vario us scales whose production has important strategic significance. For reliable functioning of metallurgical enterprises, the adequate power supply system with high energy efficiency and minimum possible power consumption is required. Most receivers of metallurgical production belong to the first category of reliability of electricity supply that makes high demands on their power systems. The power supply systems of metallurgical companies are considered. It is shown that the power supply system may be affected by various negative factors, including the switching overvoltages. Such overvoltages can have high frequency character and occur when triggered vacuum swit ches. Their appearance is caused by the arc interruption mechanism in vacu um (arc reignition, current chopping, voltage escalation). Overvoltages reduce level of reliability of power supply systems that can lead to long outage of responsible consumers. Most vulnerable to overvoltages elements of power supply systems are electric motors whose isolation has the smallest margin of electric strength. Typical means of protection (spark-gapped arresters, metal-oxide surge arresters, spark gaps) are ineffective for limiting the overvoltages with high frequency character. To limit overvoltages of this kind protective RC circuits are increa singly used. However, their application must be accompanied by fairly accurate simulation, because the wrong choice of their parameters can lead to deterioration of switching process. All this causes importance of the problem of choosing the optimal parameters of protective RC circuits and their connection schemes. The typical power supply scheme was identified and simulation of the switching overvoltages arising in the similar scheme was carried out. MathLab package was applied to build the model of a fragment of the power supply system. Du ring crea tion of the model there were used already known provisions and provisions for the first time offered by the authors that provide the larger accuracy to the mo del. The received results are presented in the form of oscillograms and comparison of experimental and calculated data was performed. The relative error of the results was less than 5 %. The recommendations for the construction of rational power supply systems of metallurgical companies allowing to reduce negative disturbances, acting on the such systems are given.
MATERIAL SCIENCE
In physical metallurgy practice the analysis of phase and structural transformations often is made through the methods based on measurement of magnetic characteristics of metal body; in these methods measurements of coercive forces, Curie points, the analysis of frequency dependence of magnetic properties and Barkhausen effect are used. In this paper, the technique based on change of magnetic permeability of the sample at its continuous cooling from temperatures above Curie point (Tc ), through the martensite transformation start temperature (Ms ) to the final stages of transformation (Mf ) is applied. The method essence consists in measurement of frequency fluctuations in oscillatory circuit based on a chain “L (inductance coil, as a magnetic-test coil) – C (precision condenser)”. Explored metal sample played a magnetic core role in the measuring coil. For supervision of phase transformations effects, the sample was warmed up preliminary and then quickly transferred to the coil. The main effects were associated with the transition through the Curie point of ferrite, as well as with the transformation of austenite into martensite. The measuring scheme has allowed fixing Curie point of ferrite for various steels in the range of 580 – 780 °С with accuracy of 5 ºС, at the same time martensite transformations interval had extent not less than 100 ºС. It has been shown that magnetometric analysis technique, based on deviation of magnetic state of ferromagnetic phases in material at near Curie temperature, allows to define quantity of δ-ferrite in the mixed structure (martensite + δ-ferrite) at its various morphology that is not always achievable by traditional metallographic methods. Magnetometric analysis of the samples subjected to primary high-temperature quenching and the subsequent heating on lower temperatures with cooling in the measuring coil unit, has allowed defining temperatures of Ac1 and Ac3 in studied steels which were in the range of 760 – 1020 ºС. Determination of the point Ac1 for 15Cr13Mn5MoWVB steel (780 – 790 °С) allowed setting the temperature of its tempering after quenching equal to 780 °С, closest to the temperature of Ac1 , that made it possible to reduce the rate of decrease in hardness at the subsequent long ageing (up to 3000 hours) of this steel at 720 °С. The developed method for determining the temperatures Ac1 and Ac3 in steels is additional to similar methods based on measurements of thermal, dilatometric and mechanical characteristics and makes it possible to make a more reasonable choice of these temperatures. The proposed methodology in the current hardware implementation is applicable only to those steels where the austenite at its overcooling is sufficiently stable against processes of decomposition by diffusion mechanism, but undergoes a complete transformation with the aid of the martensitic mechanism upon reaching Ms and Mf points (this means that the time of the incubation period at the level of “nose” of the S-shaped decomposition curve should be not less than 5 minutes); for other steels, including austenitic, carbon and ordinary low alloy engineering steels this technique is inapplicable.
Steels of various strength classes were distributed and analyzed according to deformation resistance parameter. It is considered that the deformation process in the thermodynamic aspect appears to be a dissipative effect: a part of kinetic energy of the external mechanical action transfers to the internal energy of the deformable metal with the formation of a certain dislocation structure. Because of it the energy criteria were proposed for the deformability of metal, determined in the standard tensile test. The basis of these criteria is the deformation work, which was determined by the area of the tension diagram. In this case, the absorbed energy determines the unit rupture work, and the rate of energy absorption determines the metal deformation resistance (compliance of plastic deformation). Quantitative assessment of dissipation effect demonstration with matching of the unit rupture work values and the compliance criteria was evaluated. The study was carried out using standard tensile tests of samples, made of steels with various strengths, achieved due to chemical composition (alloying) and heat treatment, used to manufacture products of various structural purposes. Herewith in the selected complex of steels, the yield strength range was 210 – 1660 MPa, the ultimate strength was 840 – 1940 MPa. Consequently, it was established that unit rupture work of the concentrated deformation much exceeds the unit rupture work of the uniform deformation. The criteria of the concentrated deformation compliance are much lower than the criteria of uniform deformation compliance, moreover, there is a noticeable correlation between it. The correlation can be considered as a demonstration of the structural evolution of metal in both stages of its deformation, in which, in the process of self-organization of dissipative system, such as deformable metal, the dislocation density serves as an internal parameter controlling the evolutionary transformation. The correlation between the compliance criteria and the ultimate stresses under uniform deformation and fracture was established. Thereby, the ranking of steels with different strengths per energy, absorbed during deformation, was conducted. In the applied aspect, the numerical values of the unit rupture work and the compliance criterion can be used for predicting the behavior of steels of various strength classes under mechanical treatment and mechanical action during operation.
The wear resistance of PCD cutting elements of GES 1313 model of E6 in the form of cylinders with a diameter of 13.44 mm and a height of 13 mm was studied when cutting granite and abrasive wheels by turning at various speeds, with determining the optimum cutting speed and obtaining comparative cutting data for Mansurovsky Granite and abrasive wheels of 64C (SiC) grade in order to develop recommendations on the test conditions for PCD cutting elements. For the characteristics of wear resistance, the ratio of the decrease in the volume of diamond layer to the volume of the processed material (or the amount of the processed material) was taken into account for the same degree of wear of the cutting element. In the first case, the wear resistance was estimated in relative units, in the second case in cm3 according to the wear of the back surface in mm. When cutting granite, the cutting speed was changed from 80 to 320 m/min, when cutting abrasive wheels, the cutting speed was 500 m/min. To calculate the volume of PCD cutting elements
in the “Compass 3D” program, 3D models of their worn parts were designed, a calibration plot of the volume versus the wear size on the back cutting surface of the PCD was constructed. The cutting angle was –22°. It was shown that the change in the volume of the worn out part of the PCD is less than accuracy of the wear pad measurement to a wear value of 0.8 mm when the cutting angles varies from –20 to –25. It was found that an increase in the cutting speed from 80 m/min to 160 m/min while cutting granite in 12 times decreases the wear resistance of PCD cutting elements; the relative volume wear of PCD cutters when cutting granite is (0.01 – 0.02)·10–6, which is 20 times less than at cutting abrasive wheels of 64C grade. The relative wear resistance of PCD cutters when cutting abrasive wheels of 64C grade does not depend on the degree of blunting on the back surface to 1.4 mm, this technique can be recommended as an express method for determining the wear resistance of PCD. The implemented method with the use of “Compass 3D” program or similar engineering programs to calculate the volume of worn out part of the PCD can be used to estimate the relative abrasion resistance of abrasive and cutting materials.
PHYSICO-CHEMICAL BASICS OF METALLURGICAL PROCESSES
Thermodynamic simulation of chemical and phase transformations was made for the system of oxidized manganese ore – carbon. Prediction of thermodynamic simulation of chemical and phase transformations in the system was carried out using “Astra 4” multipurpose software system designed for simulation of equilibrium states and processes in high temperature systems with chemical and phase transformations developed in Bauman MSTU. Calculations of phase composition and characteristics of the equilibrium were carried out using the reference database on properties of individual substances. The basis for information in the database of “Astra 4” software complex are thermodynamic, thermo-physical and thermochemical properties of individual substances, which were systematized at the Institute of High Temperatures of USSR Academy of Sciences and National Bureau of Standards of the United States, published in periodicals, monographs, handbooks, and processed and calculated in Bauman MSTU. The study of simulation of chemical and phase transformations in the system were carried out in the temperature range of 1573 – 2573 K with carbon content of 5 – 10 – 15 % in the system and pressure of 0.1 MPa. During the simulation it was found that the maximum transition degree of manganese into kMn5Si3 is up to 95.3 % at T = 1873 K and 30 % content of reductant in the system, with further increase in temperature, the manganese begins to move in to the gas phase. Silicon in comparison with manganese, recovers more difficultly, and with temperature increasing begins to transit into the gas phase, the most optimal temperature interval of silicon recovery is 1773 – 1873 K with the content of reductant in the system from 15 to 30 %. The transition degree of iron (αFe , %) in the system depending on temperature and % content of the reducing agent, allowed to determine the optimal temperature range of 1773 – 1873 K when the content of the reducing agent is 15 %. Thermodynamic modeling of phase transitions of the system manganese ore – reducing agent allowed to perform the opportunity of obtaining ferro-silico-manganese from refractory oxidized manganese ore of “Western Kamys” deposit by electric smelting.
MATERIAL SCIENCE AND NANOTECHNOLOGIES
The analyses of new solutions to determine of the contact stress in zones with variable frictional forces for upsetting the rectangular strip are executed. It is shown that replacement of the Mises precise plasticity condition by an approximate condition in terms of primary stress, changes the character of curves contact stresses in the slip and dead zones, and significantly influences on the dimensions of these zones. Conditions of existence of the slip and retardation zones on the contact surface of the deformation region in depending on the friction coefficient and the relative width of the strip are installed. A method for determining efforts of the upsetting for bizonal and three-zone curves of contact stresses is developed. Comparison of the results with known experimental and theoretical data has done. The estimation of error calculation effort of upsetting by the engineering method is obtained.
IN ORDER OF DISCUSSION
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