METALLURGICAL TECHNOLOGIES
The improvement of operational properties of metal parts during the laser surface treatment can be obtained by modifying the melt with the prepared nano-sized particles of refractory compounds (carbides, nitrides, and others.). It allowsthe number of crystallization centersto be increased, the structure to be grinded and the uniformity of the solidified metal to be raised. It is known that thermocapillary convection promotes the homogeneous distribution of materials penetrating into the molten metal. It is also known that the presence of surface-active substances in the melt influences the character of convection. There is evidence that the structure of flow in the melt depends on the amount of surface-active substances in the metal. Therefore, the studies were conducted to obtain data on the relationship of characteristics of metal processing by laser and the uniformity degree of modifying additives distribution. Using the numerical modeling the effects of characteristics of pulsing laser action on allocation of modifying particles are estimated at the presence of surface-active substance in metal. With the help of mathematical proposed model the following non-stationary processes are considered: heating and melting of the metal, heat transfer in the melt, fluid motion, nucleation and growth of the solid phase after termination of the pulse. During the numerical realization of the model the heat conduction equation was firstly solved. Upon appearance of molten metal the boundary of the liquid phase was determined. Further the coupled equations of convective heat transfer and motion of an incompressible fluid were solved. After the laser pulse termination, the calculations are continued until the complete solidification of the substrate material is achieved. It was supposed that modifying nano-sized particles under the influence of convective flows penetrate into depth of a melt from its surface. The movement and distribution of particles in a fluid was modeled using markers. The movement of the markers was determined by the local velocity of the melt. According to the results of numerical experiments, the effect of the parameters of pulsed laser action on the nature of the flow and distribution of the particles in the melt were determined. Optimum parametersfor the melting of the metalsubstrate by a laser pulse are proposed for various surface-active substances concentrations.
The paper presents the results of simulation of rolling of balls precise in mass with diameters of 93 and 125 mm in screw calibers in QForm-3D and DEFORM-3D, the stages and initial data of creating a virtual model of ball-rolling mill are described. The stress state of the metal in characteristic points along the rolling axis was analyzed: stress intensity, stress tensor components, average normal stress. The results of mass measurements of balls rolled on new and worn rolls are presented. The quality check of the inner layers of metal was carried out and the hardness of the rolled balls was measured along the vertical and horizontal axes of ball symmetry. Investigation of metal deformation in simulation of ball rolling has shown that heated billet in form of hot-rolled steel rod is well gripped by rolls, rolling process is stable without slipping. Billet metal fills the gauges completely. There are no gaps observed between metal and gauges walls. Breaker cores connecting molded balls are completely separated in the mill rolls. In this case, core is cut by the rolls flange and is pressed into the ball body. Separated ball continues to roll in gauge finishing section, core remains are smoothed, and completely formed ball with a smooth surface appears from the rolls. It was established that in stress-strain state modeling all components of stress tensor have negative value, that is, all components of stress tensor during balls rolling are compressive. Statistical processing of data on weighing rolled balls with a diameter of 93 mm and 125 mm shows that deviation of mass from the nominal does not exceed 1 %. Measurements of hardness along the balls diametric section shows absence of hardness failures in the inner layers of rolled metal, which indicates a good quality of core zone.
RESOURCE SAVING IN FERROUS METALLURGY
MATERIAL SCIENCE
The paper presents the analysis of strain hardening in monocrystals of single-phase disordered alloy Ni3 Fe. These monocrystals are subjected to compression at room temperature. The compression axis is parallel to [001] crystallographic direction. The strain curve of monocrystals with [001] orientation is characterized by several stages conditioned by a certain sequence of substructural transformations. Ni3 Fe alloy with monocrystals of atomic short-range order possesses an average value of stacking fault energy. Plastic deformation enables the low-energy evolutionary branch of substructure: plane dislocation clusters → knitted structure → striple structure. The linear stage of the alloy strain hardening is connected with the formation of non-homogeneous knitted dislocation structure. TEM images of this structure allow measuring the free distances between the different dislocation locks formed along the dislocation line due to the dislocation intersections of different slip systems. Using the parameters measured for the monocrystal knitted structure, the contribution of strain-hardening mechanisms to shear stress was evaluated. These mechanisms include dislocation intersection, threshold creep, formation and destruction of dislocation junctions, crossing of Lomer–Cottrell and Hirth dislocation barriers and spot defect generation. The formation laws for long-range stresses and elastic interaction between dislocations were studied and the static and dynamic stress contribution to the total stress was determined. To consider the non-homogeneity of knitted dislocation structure, the contributions are detected individually for its dense and loose areas. The estimation of partial contribution made by each mechanism indicates that the main impact to deformation resistance of monocrystals oriented for multiple slip is made by the dislocation hindering, caused by contact interaction between moving and forest dislocations. The deformation growth enables the density increase in the dislocation locks (thresholds and junctions) along the dislocation line, caused by strain hardening of alloy FCC having an atomic short-range order.
PHYSICO-CHEMICAL BASICS OF METALLURGICAL PROCESSES
Increase in productivity and reduction of resource and energy capacity in steel production in converters predetermine development of technological measures and improvement of design of aggregates providing preheating of scrap and other charge materials, intensification of afterburning of waste gases in working space of steelmaking unit and redox processes in liquid bath while maintaining satisfactory durability of blowing devices and lining of the converter. Using fuel-oxygen combustion flames in converter process allows solving a number of multi-purpose technological problems. Combustion of fuel in working space of converter during formation of jet or use of submerged combustion flames significantly changes hydrodynamic pattern in reaction zones and liquid bath. Thermodynamic methods have been used to determine dynamics of combustion processes of gaseous fuels and oxidation of converter bath elements during their interaction with high-temperature flame combustion products. Calculation of the process of flame interaction with chemical elements of the bath was carried out for equilibrium conditions. It was established that use of combustion flames changes composition of gas phase in working space of converter, in which H2 and H2O are formed in addition to those traditionally present when oxygen is blown with O2 , CO, and CO2 . Presence of these gases changes thermal regime and oxidizing ability of the gas phase. When burning gas-oxygen fuel, optimal composition of initial gas mixture (natural gas + oxygen) should correspond to a ratio of 100 % CH4 + 69 % O2 , while a vapor-gas phase containing 40 % of CO2 and 60 % of H2O is formed as a product of oxidation reactions. The total enthalpy of gas-oxygen fuel combustion at converter melting temperatures with oxygen excess ratio of more than 1.0 (up to 2.0) is approximately 200 kJ/mole of the initial reagents, with methane oxidation by carbon dioxide (–7) ÷ (–14.5) KJ/mole of initial reagents) at 1800 K and the process becomes endothermic at temperatures over 2000 K (ΔH2200 = (+7.7) ÷ (15.4) kJ/mole); with water vapor gas oxidation (ΔH1800 – 2200 = (+19.5) ÷ (+70) kJ/mole of the initial reagents. Therefore, only when the methane is oxidized with oxygen temperature of flame can be more than 1800 K. Use of carbon dioxide, water vapor as an air oxidizer does not give necessary thermal effect.
ECOLOGY AND RATIONAL USE OF NATURAL RESOURCES
INFORMATION TECHNOLOGIES AND AUTOMATIC CONTROL IN FERROUS METALLURGY
ISSN 2410-2091 (Online)