METALLURGICAL TECHNOLOGIES
The article gives the review of the influence of various alloying components and impurities on chromium and chromium-base alloys attributes and also the review of the production methods of these alloys. The metalo-physical and physico-chemical principles of the production of dispersion-strengthed alloys are examined. The coagulation of dispersed particulates during heating of metal and hot metal endurance “Ostwald Maturity” is examined. It was found that those processes are linked with the excessive free energy (Gibbs energy) reduction. The conclusion about the necessity of thermodynamical estimation of pointed out processes was done and the results are described.
The results of studies of basalt implementation in the production of chromite pellets are described with its influence on the quality of wet, dry and fi red pellets. It is shown that the use of basalt allows fully to deduce bentonite and coking fines from the charge, to reduce the burning temperature from put into practice 1400 °C to 1250 – 1300 °C, as well as to produce fi red pellets corresponding to the technical requirements.
Model of ideal associated solutions is quite acceptable for description of thermodynamic properties of liquid metal binary solutions with positive deviations of thermodynamic activity from the Raoult law. The use of model for prediction of thermodynamic properties of real multicomponent solutions is possible under condition of independent definition of thermodynamic properties of “self-associates”.
RESOURCE SAVING IN FERROUS METALLURGY
ECOLOGY AND RATIONAL USE OF NATURAL RESOURCES
The authors describe the effect of low-alkaline red mud on the composition and structural characteristics of pelletized charge of JSC “Severstal”, consisting of ferruginous quartzites of Olenegorskoe and Yakovlevskoe deposits and Kovdor magnezite ores. It is proved that in the process of pelletizing low-alkaline red mud additives contribute to improve the granulation process, increasing the average diameter of the granules. The distribution of the main melt forming elements was shown for fractions of pelletized charge.
MATERIAL SCIENCE AND NANOTECHNOLOGIES
The paper is devoted to the effect of pulsed electron-beam treatments with different energy densities Е1 = 15 J/cm2, Е2 = 20 J/cm2 и Е3 = 30 J/cm2 on the change of structural and phase states in the NiTi surface layers. It is revealed that in the diffraction patterns of NiTi specimens with one side irradiated by a low-energy high-current electron beam the refl ections B2 phase and martensite phase B19′ are observed. By increasing the energy density from Е1 = 15 J/cm2 to Е3 = 30 J/cm2 the content of martensite phase B19′ increases from 5 % to 80 %. It is also revealed that the surface layer is melted to the thickness 8–10 μm, and in this layer the Ti2Ni phase dissolves. The dis-solution of Ti2Ni phase leads to a change in the concentration of Ti and Ni. It is established that the modifi ed B2 phase in the melted layer is enriched with titanium as compared with its original content in the B2 phase up to irradiation. It is revealed that B19′ phase formation occurs when the surface layers of the samples TiNi are treated with pulsed electron beams with lower values of the energy density in the beam (Е1 = 15 J/cm2, Е2 = 20 J/cm2). In the samples treated with pulsed elect ron beams with greater energy density in the beam Е3 = 30 J/cm2, the surface layer to the entire depth of penetration of X-ray beam is in the martensitic state.
Phase and chemical compositions, structures and microhardness of diffusion coatings, containing titanium and aluminium, were studied on samples of steel 12Cr18Ni10Ti. Depending on the type of treatment the multilayer coatings on titanium carbide and nitrite base, intermetallics and oxides of titanium, aluminium, nickel, chromium, iron, as well as solid solutions of titanium and aluminium in austenite are formed in steel. It was found that during chemical-thermal treatment the titanium nitrite layer has a function of a barrier, delaying the aluminium and titanium diffusion into a base and the base components – into a coating.
SHORT REPORTS
The authors proposed a method of quantitative estimation of heating temperature during cold rolling of tubes with specified performance. The formula for calculating the deformation heating is described resulting from the law of energy conservation during plastic deformation. As a result the authors showed an example of using the proposed formulas for evaluating the reduction effort rolling along a certain route. The possibility of intensification of rolling process by temperature heating is described.
The influence of the temperature mode in the rotary furnace on lime quality is established experimentally in laboratory and industrial conditions with its impact on the slag mode during electric smelting of steel in electric arc furnaces.
The resistant boron-containing coatings with low thermal conductivity were used to enhance durability and to reduce heat losses through the air tuyeres. The possibility of solving the task was shown on the example of the trials of two experienced tuyeres.
The calculation of sinter chemical composition from chromite fines and various silica and alumina-silica fluxing agents was made and described.
ISSN 2410-2091 (Online)