METALLURGICAL TECHNOLOGIES
Within the limits of the theory of flat deformation the problem for the balance equations in displacements that has allowed to define a field of thermoelastic stresses in a forge ingot of many-sided section in the course of its cooling or heating is put and decided. Tangent normal stresses in blankets are stretching and exceed an elasticity limit when difference of temperatures between an axis and an ingot side reaches the greatest value. The method of lines of sliding receives a field of the plastic stresses arising at free forging of an ingot in mixed strikers. It is received a total stress tehsor of thermoelastic pressure and plastic hammer forging pressure, showing possibility of formation of longitudinal superficial cracks. Results are enclosed to hammer forging a 7-ton ingot of 8-faced section from the alloyed steel at temperatures 1100, 850 and 680 °C.
Presented is the method of determining air consumption in cupola process by calculating quantity of fuel burned per time unit, using experimen- tal values of fuel carbon combustion rate or cupola capacity. Laboratory and production tests show that actual air consumption is always 5,4 – 5,6 % higher than estimated, which is due to air leaks through the control valves on the pipelines to the tuyeres, and gas leaks when opening metal and slag tap holes.
Studied are thermodynamics, conditions and mechanism of the synthesis of boride CrB2 and carbonitride Cr3(C0,8N0,2)2 with powdered chromi- um, boron, methane (natural gas) in plasma flow of nitrogen. Identified and described is the single-channel mechanism of the processes studied with chromium vapor, its condensation products, boron and hydrogen cyanide, implemented by vapor – melt – crystal circuit. The temperature zones in which the process of formation of gaseous chromium-boron and chromium-carbon reaction mixtures, boride- and carbonitride- forming take place.
The analysis of the CaO·SiO2 – CaO·Al2O3·2SiO2 – CaO·TiO2·SiO2 system is carried out. Thermodynamic analysis of univariant and invariant crystallization processes showed that at invariant equilibrium and crystallization along the boundary curve separating the field of crystallization of anorthite and sphene crystallization is carried out by peritectic reactions. The parameters of the invariant state of the system are determined as follows (t = 1513 К, аСaO = 0,0407, аSiO = 0,5268, аAl O = 0,00003, аTiO = 0,005). Presented is the revised version of the system diagram.
The influence of the exposure duration of nanosecond electromagnetic pulses (NEMI) on crystallization, structure and properties (hardness, density, microhardness of structural parts, corrosion resistance, wear-resistance) of low-silicon cast iron is examined. It is found that the increase in duration of NEMI exposure on the melt results in the increase of starting temperature for eutectic and eutectoid transformation. Physical and mechanical properties of cast iron vary considerably depending on the melt exposition duration (MED) according to extreme dependence with maxima and minima properties under of 10 – 15 min. For example, the thermal conductivity of the melt increases two or more times.
MATERIAL SCIENCE AND NANOTECHNOLOGIES
TOPICAL COLLECTION OF ARTICLES «NANOSTRUCTURED MATERIAL SCIENCE»
Regularities of structure modification under boundary lubrication friction of 110Mn13 steel in as supplied condition and after impact ultrasonic treatment were studied. Based on results of transmission electron microscopy the peculiarities of changing fine structure in surface and subsurface layer are analyzed. On the basis of obtained data the revealed difference in wear pattern of specimens of both types are interpreted.
The results of comparative investigation of microstructure and mechanical properties are presented for zirconium alloyed with niobium (1 mass. % Nb). Zirconium was obtained by abc-pressing method. ABC-pressing method allows to produce ultrafine grained structure with the decreasing average size of the zirconium matrix elements in range from 0,55 μm to 0,28 μm. The rolling provides the formation of ultrafine-grained states with the zirconium structural elements size equal to 0,2 μm and the microhardness is equaled to 2800 MPa. Between the microhardness and the value of d–1/2 (d is the average size of the structural elements) linear dependence was found. It indicates a Hall-Petch ratio.The increase of microhard- ness of ultrafine zirconium alloy is attained by reducing of structure elements and formation of ultra-grained oxides.
Influence of a pulse current on deformation behavior is studied at tension and a room temperature of nanostructured shape memory TiNi alloy. The direction and amplitude of stress jumps in investigated material sharply differ from those, observed in pure metals and alloys without phase transformations.
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