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Metallographic studies of the alloy of Co – Cr – Fe – Mn – Ni system

https://doi.org/10.17073/0368-0797-2026-3-258-264

Abstract

In conditions of the Scientific and Production Center “Welding Processes and Technologies” of the Siberian State Industrial University, the developed flux-cored wires of the Co – Cr – Fe – Mn – Ni system were surfaced by automatic arc welding under a layer of flux. Chemical composition of the deposited coating samples was determined using the atomic emission method on the DFS-1 spectrometer and the X-ray fluorescence method on the XRF-1800 spectrometer. The research results indicate the possibility of obtaining coatings consisting of 60 – 70 % iron and 30 – 40 % alloying elements. Microstructural studies of the samples were carried out using the metallographic microscope METAM RV-34 and the NEXSYS ImageExpert software package. The deposited samples contain point oxides of grade 2a, non-deformable silicates of grade 4a, b. Compared with the substrate (09G2S steel), the resulting deposited layers of the samples are noticeably cleaner, however, K4 sample has less contamination. Microstructure of the first deposited layers is represented by needle-like martensite, which is confirmed by the results of microhardness measuring. Subsequent layers of the deposited samples are represented by an austenitic crystal structure. Moreover, the structure has an elongated (dendritic) structure, which is inherent in structures obtained by arc welding. The authors studied the microhardness distribution using the HVS-1000 microhardness tester according to Micro-Vickers GOST 9450 – 76. The results indicate the production of an alloy with a hardness slightly higher than that of the substrate used, while it is worth noting that the deposited layer contains zones with twice hardness. Most often, an increase in hardness is observed on the first deposited layers.

About the Authors

R. E. Kryukov
Siberian State Industrial University
Russian Federation

Roman E. Kryukov, Dr. Sci. (Eng.), Prof. of the Chair of Mechanics and Machine Engineering

42 Kirova Str., Novokuznetsk, Kemerovo Region – Kuzbass 654007, Russian Federation



S. V. Konovalov
Siberian State Industrial University
Russian Federation

Sergei V. Konovalov, Dr. Sci. (Eng.), Vice-Rector for Research and Innovation

42 Kirova Str., Novokuznetsk, Kemerovo Region – Kuzbass 654007, Russian Federation



A. R. Mikhno
Siberian State Industrial University
Russian Federation

Aleksei R. Mikhno, Director of the Scientific and Production Center “Welding Processes and Technologies”

42 Kirova Str., Novokuznetsk, Kemerovo Region – Kuzbass 654007, Russian Federation



I. A. Panchenko
Siberian State Industrial University
Russian Federation

Irina A. Panchenko, Cand. Sci. (Eng.), Senior Researcher of the Department of Scientific Research

42 Kirova Str., Novokuznetsk, Kemerovo Region – Kuzbass 654007, Russian Federation



References

1. Mikhailitsyn S.V., Zvereva I.N., Sheksheev M.A. Welding and Surfacing Materials. Moscow: Infra-Engineering; 2020:228. (In Russ.).

2. Raikov S.V., Gromov V.E., Kryukov R.E., Knyazev A.S. Wear-Resistant Deposited Layers: Properties, Structure and Phase Composition. Novokuznetsk: Polygraphist; 2024:179. (In Russ.).

3. Barinov S.V., Zagorodskikh B.P., Simdyankin A.A. A study of the wear resistance of parts with an inhomogeneous friction surface. Journal of Friction and Wear. 2003;24(5):568–572.

4. Kozyrev N.A., Shurupov V.M., Kushnarenko N.N., Kozyreva O.E., Titov D.A. The usage of tungsten-containing ores at welding. Izvestiya. Ferrous metallurgy. 2015;58(8): 567–571. (In Russ.). https://doi.org/10.17073/0368-0797-2015-8-567-571

5. Kumar V.A., Murty S.V.S.N., Gupta R.K., Rao A.G., Pra­sad M.J.N.V. Effect of boron on microstructure evolution and hot tensile deformation behavior of Ti-5Al-5V-5Mo-1Cr-1Fe alloy. Journal of Alloys and Compounds. 2020;831:154672. https://doi.org/10.1016/j.jallcom.2020.154672

6. Artem’ev A.A., Sokolov G.N., Zorin I.V., Dubtsov Yu.N., Antonov A.A., Lysak V.I. Formation of structure in clad abrasion-resistant alloys of the Fe – Cr – C – Mo – Ni – Ti – B system under the effect of ultrafine particles of titanium nitride. Metal Science and Heat Treatment. 2020;61(11-12): 724–730. https://doi.org/10.1007/s11041-020-00490-8

7. Winkelmann H., Badisch E., Varga M., Danninger H. Wear mechanisms at high temperatures. Part 3: Changes of the wear mechanism in the continuous impact abrasion test with increasing testing temperature. Tribology Letters. 2010;37(2):419–429. https://doi.org/10.1007/s11249-009-9534-3

8. Kolokolov E.I., Pirozhkov R.V., Tomilin S.A. Applicability of 110G13P type powder steel for production of consolidation details of high parameters power fittings. In the World of Scientific Discoveries, Series B. 2014;2(2):29–35.

9. Kozyrev N.A., Titov D.A., Starovatskaya S.N., Shurupov V.M., Goryushkin V.F. The influence of the introduction of the charge flux-cored wire system with C – Si – Мn – Сr – W – V carbon-fluorine-containing additives and nickel. Izvestiya. Ferrous Metallurgy. 2014;57(6):31–33. (In Russ.). https://doi.org/10.17073/0368-0797-2014-6-31-33

10. Kozyrev N.A., Kryukov R.E., Shurupov V.M., Kibko N.V., Bashchenko L.P. Tungsten recovery from oxide during flux cord wire surfacing. Izvestiya. Ferrous Metallurgy. 2019;62(3):215–221. (In Russ.). https://doi.org/10.17073/0368-0797-2019-3-215-221

11. Tseng S.F., Hung T.Y., Chang C.M. Mechanical and microstructural properties of additively manufactured Ti–6Al–4V stents with CO2 laser postannealing treatment. The International Journal of Advanced Manufacturing Technology. 2022;119(9-10):6571–6581. https://doi.org/10.1007/s00170-021-08381-9

12. Grigorenko G.M., Korzhik V.N., Adeeva L.I., Tunik A.Yu., Stepanyuk S.N., Karpets M.V., Doroshenko L.K., Lyutik N.P., Chaika A.A. Peculiar features of metallurgical processes at plasma-arc spraying of coatings, made of steel wire with powder fillers В4С and B4C+ZrO2 . Bulletin of the Azov State Technical University. Series: Technical Sciences. 2016;(32):125–137. (In Russ.).

13. Peleshenko S., Korzhyk V., Voitenko O., Khaskin V., Tkachuk V. Analysis of the current state of additive welding technologies for manufacturing volume metallic products (review). Eastern-European Journal of Enterprise Technologies. 2017;3(1(87)):42–52. https://doi.org/10.15587/1729-4061.2017.99666

14. Sheksheev M.A., Shiriaeva E.N., Mikhailitsyn S.V. Investigation of the influence of ultrafine particles of refractory materials on the formation of the structure and properties of the deposited metal. AIP Conference Proceedings. 2022;2503(1):060007. https://doi.org/10.1063/5.0099350

15. Krokhalev A.V., Kharlamov V.O., Kuz’min S.V., Lysak V.I., Grinberg B.A. Fine structure of interphase boundaries in hard alloys of the chromium carbide–titanium system. Russian Journal of Non-Ferrous Metals. 2016;57(5):504–508. https://doi.org/10.3103/S1067821216050096

16. Malushin N.N., Romanov D.A., Kovalev A.P., Osetkovskii V.L., Bashchenko L.P. Structural-phase state of a high-hardness heatresistant alloy formed by plasma cladding in a nitrogen atmosphere and high-temperature tempering. Russian Physics Journal. 2020;62(10):1865–1870. https://doi.org/10.1007/s11182-020-01917-8

17. Malushin N.N., Valuev D.V. Plasma surfacing and nitriding of deposited parts of the mining and metallurgical complex. Mining Information and Analytical Bulletin (scientific and technical journal). 2012;(12):105–108. (In Russ.).

18. Belkahla Y., Mazouzi A., Lebouachera S.El.I., Hassan A.J., Fides M., Hvizdoš P., Cheniti B., Miroud D. Rotary friction welded C45 to 16NiCr6 steel rods: statistical optimization coupled to mechanical and microstructure approaches. The International Journal of Advanced Manufacturing Technology. 2021;116(7):2285-2298. https://doi.org/10.1007/s00170-021-07597-z

19. Liu J.-Z., Zhang L.-J., Yang H.-X., Xie M.-X., Shang X.-T., Zhang J.- X. Enhancement of corrosion protection performance of SUS304/Q235B dissimilar metals lap joint through fiber laser. The International Journal of Advanced Manufacturing Technology. 2018;96(1-4):789–802. https://doi.org/10.1007/s00170-018-1634-5

20. Zavdoveev A., Pozniakov V., Baudin T., Kim H.S., Klochkov I., Motrunich S., Heaton M., Aquier P., Rogante M., Denisenko A., Gajvoronskiy A., Skoryk M. Optimization of the pulsed arc welding parameters for wire arc additive manufacturing in austenitic steel applications. The International Journal of Advanced Manufacturing Technology. 2022;119(7-8):5175–5193. https://doi.org/10.1007/s00170-022-08704-4

21. Yadaiah N., Bag S., Paul C.P., Kukreja L.M. Influence of self-protective atmosphere in fiber laser welding of austenitic stainless steel. The International Journal of Advanced Manufacturing Technology. 2016;86(1-4):853–870. https://doi.org/10.1007/s00170-015-8194-8

22. Liu H.H., Wang L.B., Liu W.J., Li L.Y., Yue J.F. Influence of AC magnetic field on the cladding layer during the micro beam plasma welding of austenitic stainless steel. The International Journal of Advanced Manufacturing Technology. 2018;97(9):3459–3468. https://doi.org/10.1007/s00170-018-2182-8

23. Tabatchikov A.S., Korobov Yu.S., Razikov N.M., Onishchenko L.A. Development of Technology for Manufacturing Electrodes and Powder Wires for Welding and Related Processes. Yekaterinburg: Ural Publishing House University; 2023:112. (In Russ.).


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For citations:


Kryukov R.E., Konovalov S.V., Mikhno A.R., Panchenko I.A. Metallographic studies of the alloy of Co – Cr – Fe – Mn – Ni system. Izvestiya. Ferrous Metallurgy. 2026;69(3):258-264. (In Russ.) https://doi.org/10.17073/0368-0797-2026-3-258-264

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ISSN 0368-0797 (Print)
ISSN 2410-2091 (Online)