STUDY OF THE KINETICS OF CARBON OXIDATION BY ARGON-OXYGEN PLASMA IN CHROMIUM-CONTAINING MELTS
https://doi.org/10.17073/0368-0797-2016-9-656-662
Abstract
The article describes the investigation of treatment processes of such alloys as Fe – Cr and Fe – Cr – Ni by oxygen-containing plasma. The laboratory unit, which is a plasma furnace with a tungsten cathode and a water-cooled copper anode, can simulate processes that occur in the contact area of plasma arc and melt surface. It was also developed a mathematical model describing the processes occurring in the interaction between plasma torch and surface of the molten metal. According to the results of the experiments the authors have determined the kinetic parameters of decarburization process of high-chromium melts by argon-oxygen plasma. The results allow to conclude that treatment of high-chromium melts by plasma which contents less than 15–17 % of oxygen provides a high degree of decarburization with low chromium haze. The comparison of model calculations and experimental data has shown good reproducibility.
About the Authors
B. A. RumyantsevRussian Federation
Postgraduate of the Chair “Metallurgy of Steel and Ferroalloys”
O. A. Komolova
Russian Federation
Cand. Sci. (Eng.), Assist. Professor of the Chair “Metallurgy of Steel and Ferroalloys”
K. V. Grigorovich
Russian Federation
Coresponding Member of Russian Academy of Sciences, Dr. Sci. (Eng.), Professor, Head of the of the Chair “Metallurgy of Steel and Ferroalloys”, Head of the Laboratory
A. K. Garber
Russian Federation
Cand. Sci. (Eng.), Assist. Professor of the Chair “Metallurgy of Steel and Ferroalloys”
Ya. I. Tabakov
Russian Federation
Research Engineer
References
1. Gol’dshtein M.I., Grachev S.V., Veksler Yu.G. Spetsial’nye stali [Special steel]. Moscow: MISIS, 1999, 408 p. (In Russ.).
2. Tufanov D.G. Korrozionnaya stoikost’ nerzhaveyushchikh stalei, splavov i chistykh metallov [Corrosion resistance of stainless steels, alloys and pure metals]. Moscow: Metallurgiya, 1982, 641 p. (In Russ.).
3. Babakov A. A., Pridantsev M. V. Korrozionnostoikie stali i splavy [Corrosion-resistant steels and alloys]. Moscow: Metallurgiya, 1971, 319 p. (In Russ.).
4. Rimkevich V.S., Sisev A.A., Muruev S.V., Blokhin M.V. Opportunities for improvement of the traditional smelting of stainless steels. Chernaya metallurgiya. Byul. in-ta “Chermetinformatsiya”. 2012, no. 8, pp. 23–28. (In Russ.).
5. Grigoryan V.A., Belyanchikov L.N., Stomakhin A.Ya. Teoreticheskie osnovy elektrostaleplavil’nykh protsessov [Theoretical foundations of EAF processes]. Moscow: Metallurgiya, 1987, 272 p. (In Russ.).
6. Zhovtyanskii V.A. Electric arc – the basis of thermal plasma applications. Part I. General properties of the plasma arc and heat transfer characteristics of the processes. Promyshlennaya teplotekhnika. 2007, vol. 29, no. 4, pp. 13–22. (In Russ.).
7. Cherednichenko V.S., Kuz’min M.G., An’shakov A.S. Plasma systems for melting and recovery of metals. Elektrometallurgiya. 2009, no. 9, p. 20 – 27. (In Russ.).
8. Laktionov A.E., Stomakhin A.Ya., Grigoryan V.A. etc. Temperature of the metal surface at plasma melting. Izvestiya VUZov. Chernaya metallurgiya = Izvestiya. Ferrous Metallurgy. 1979, no. 7, pp. 49–52. (In Russ.).
9. Komolova O.A. Modelirovanie vzaimodeistviya komponentov shlakovoi i metallicheskoi faz pri proizvodstve stali, razrabotka algoritmov i programmnogo obespecheniya dlya opisaniya tekhnologicheskikh protsessov: avtoref. dis…. kand. tekhn. nauk [Modeling of the components interaction of slag and metal phases in the production of steel, development of algorithms and software for the processes description: Extended Abstract of Cand. Sci. Diss.]. Moscow: MISiS, 2014, 24 p. (In Russ.).
10. Klyuev M.M. Plazmenno-dugovoi pereplav [Plasma-arc remelting]. Moscow: Metallurgiya, 1980, 253 p. (In Russ.).
11. Farnasov G.A., Fridman A.G., Karinskii V.N. Plazmennaya plavka [Plasma melting]. Moscow: Metallurgiya, 1968, 171 p. (In Russ.).
12. Trusov B.G. TERRA software system for the simulation of chemical and phase equilibriums in plasma-chemical processes. In: Materialy III mezhdunarodnogo simpoziuma po teoreticheskoi i prikladnoi plazmokhimii [III-th International Symposium on Theoretical and Applied Plasma Chemistry]. Ivanovo: 2002, pp. 217–220. (In Russ.).
13. Yavoiskii V. I. Teoriya protsessov proizvodstva stali [Theory of steel production]. Moscow: Metallurgiya, 1967, 792 p. (In Russ.).
14. Fischer W.A., Janke D., Stahlschmidt K. Die Verdampfung von Eisen und seiner Begleitelemente Kupfer und Mangan beim Schwebeschmelzen unter vermindertem Druck. Archiv f.d. Eisenhuttenwesen. 1974, b. 45, no. 11, S. 757–764.
15. Karasev R.A. Kinetics and mechanism of interaction of liquid ironcarbon melts with the gas phase CO – CO2 . V. kn.: Kinetika i termodinamika vzaimodeistviya gazov s zhidkimi metallami [In: Kinetics and thermodynamics of the interaction of gases with liquid metals]. Moscow: Nauka, 1974, pp. 82–87.(In Russ.).
Review
For citations:
Rumyantsev B.A., Komolova O.A., Grigorovich K.V., Garber A.K., Tabakov Ya.I. STUDY OF THE KINETICS OF CARBON OXIDATION BY ARGON-OXYGEN PLASMA IN CHROMIUM-CONTAINING MELTS. Izvestiya. Ferrous Metallurgy. 2016;59(9):656-662. (In Russ.) https://doi.org/10.17073/0368-0797-2016-9-656-662