RECOVERY OF IRON FROM WASTE SLAG OF COPPER INDUSTRY
https://doi.org/10.17073/0368-0797-2016-9-597-607
Abstract
The authors discuss the investigation results of phase transformations in the slag of sulphuric cupreous melting during its reduction by the products of gasification of carbon at the temperatures 1100 and 1200 °С. It was experimentally found, that in belllike equipment at the temperature 1100 °С the most part of iron from dump slag of sulphuric melting of the cupreous concentrates may be reduced to metallic state by the products of carbon gasification. Subsequent rise of temperature up to1200 °Cenables to increase iron recovery. During the indirect reduction of the slag at the temperature above temperature of its melting, metallic iron concentrates mostly at the external surface of product of reduction, producing large inclusions, which may be easy extracted by magnetic separation. It’s mostly rational to reduce multilayer blend, consisting from slag layers with the thickness less than5 mmand separating them layers of grinded coal.
About the Authors
A. A. LykasovRussian Federation
Dr. Sci. (Chem.), Professor of the Chair “Physical Chemistry”
G. M. Ryss
Russian Federation
Cand. Sci. (Chem.), Assist. Professor of the Chair “Physical Chemistry”
D. G. Sharafutdinov
Russian Federation
Student
A. Yu. Pogodin
Russian Federation
Student
References
1. Gorai Bipra, Jana R.K., Premchand. Characteristics and utilization of copper slag – a review. Resources and Recycling. 2003, vol. 39, pp. 299–313.
2. Shadrunova I.V., Volkova N.A., Mastryugin S.A., Gorlova O.E. Technological, economic and ecological aspects of processing of technogenic raw material of mining and metallurgical works of the Urals. Ekologiya i promyshlennost’ Rossii. 2013, no. 8, pp. 16–21. (In Russ.).
3. Korinevskaya G.G., Muftakhov V.A., Kotel’nikova A.L., Khalezov B.D., Reutov D.S. Copper slags and questions of utilisation of mineral wastes. Mineralogiya tekhnogeneza. 2014, no. 15, pp. 244–250. (In Russ.).
4. Makarov A.B., Talalai A.G. Technogenic mineral deposits and their ecological role. Litosfera. 2012, no. 1, pp. 172–176. (In Russ.).
5. Sviridova T.V., Murzina E.A. To the issue of production and treatment of industrial waste on the territory of the Cheliabinsk region. Teoriya i tekhnologiya metallurgicheskogo proizvodstva. 2014, no. 2(15), pp. 109–112. (In Russ.).
6. Kapustin F.L., Afanas’eva M.A. The use of copper slag in the production of cements of general building purpose. Vestnik YuUrGU. Seriya “Stroitel’stvo i arkhitektura”. 2013, vol. 13, no. 2, pp. 51 –55. (In Russ.).
7. Mohammad M.Ali, Satish K.Agarwal, Ashwani Pahuja. Potentials of copper slag utilization in the manufacture of ordinary Portland cement. Advances in Cement Research. 2013, vol. 25, Issue 4, pp. 208–216.
8. Sabanova M. N., Orekhova N. N., Gorbatova E. A. Tehnological mineralogy of copper slags. Mineralogiya tekhnogeneza. 2015, no. 16, pp. 107–114. (In Russ.).
9. Huiting Shen, Forssberg E. An overview of recovery of metals from slags. Waste Management. 2003, vol. 23, pp. 933–949.
10. Bykhovskii L.Z., Sporykhina L.V. Industrial waste as a reserve to replenish mineral resources: status and development problems. Mineral’nye resursy Rossii. Ekonomika i upravlenie. 2011, no. 4, pp. 15–20. (In Russ.).
11. Kupryakov Yu. P. Shlaki medeplavil’nogo proizvodstva i ikh pererabotka [Slags of copper industry and their processing]. Moscow: Metallurgiya, 1987, 201 p. (In Russ.).
12. Sanakulov K.S., Khasanov A.S. Pererabotka shlakov mednogo proizvodstva [Processing of slags of copper production]. Tashkent: Fan, 2007, 255 p. (In Russ.).
13. Zhang Yang, Man Rui-lin, Ni Wang-dong, Wang Hui. Selective leaching of base metals from copper smelter slag. Hydrometallurgy. 2010, vol. 103, Issue 1–4, pp. 25–29.
14. Banza A.N., Gock E., Kongolo K. Base metals recovery from copper smelter slag by oxidizing leaching and solvent extraction. Hydro metallurgy. 2002, vol. 67, Issue 1–3, pp. 63–69.
15. Carranza F., Iglesias N., Mazuelos A., etc. Ferric leaching of copper slag flotation tailings. Minerals Engineering. 2009, vol. 22, Issue 1, pp. 107–110.
16. Arslan C., Arslan F. Recovery of copper, cobalt, and zinc from copper smelter and converter slags. Hydrometallurgy. 2002, vol. 67, Issue 1–3, pp. 1–7.
17. Potapov K.O., Roshchin V.E. Selective reduction and pyrometallurgical extraction of iron from copper production sludge. Vestnik YuUrGU. Seriya “Metallurgiya”. 2014, vol. 14, no. 3, pp. 25–29. (In Russ.).
18. Hongyang Cao, Jimin Wang, Li Zhang, Zhitong Sui. Study on green enrichment and separation of copper and iron components from copper converter slag: The 7th International Conference on Waste Management and Technology (ICWMT7). Procedia Environmental Sciences. 2012, vol. 16, pp. 740–748.
19. Zhu D., Chen D., Pan J., Zheng G. Chlorination Behaviors of Zinc Phases by Calcium Chloride in High Temperature Oxidizingchloridizing Roasting. ISIJ International. 2011, vol. 51, no. 11, pp. 1773–1777.
20. Gudim Yu.A., Golubev A.A. Effective methods of utilization of waste products of the metallurgical industry of the Urals. Ekologiya i promyshlennost’ Rossii. 2008, no. 12, pp. 4–8. (In Russ.).
21. Digonskii, S.V. Teoreticheskie osnovy i tekhnologiya vossta novitel’noi plavki metallov iz neokuskovannogo syr’ya [Theoretical bases and technology of smelting reduction of metals from nonagglomerated raw materials]. St. Petersburg: Nauka, 2007, 322 p. (In Russ.).
22. Lykasov A.A, Ryss G.M., Vlasova I.S. Phase transformations during reduction of the slag of sulphuric cupreous melting by the products of gasification of carbonic reducing agents at the temperature 1320 K. Vestnik YuUrGU. Seriya “Metallurgiya”. 2013, vol. 13, no. 1, pp. 24–28. (In Russ.).
23. Lykasov A. A., Ryss G.M., Borodin I.S. Iron reduction from slag of sulphuric melting by the products of carbon gasification. Izvestiya VUZov. Chernaya metallurgiya = Izvestiya. Ferrous Metallurgy. 2014, no. 1, pp. 30 – 33. (In Russ.).
24. Slag Atlas. 2nd ed. Edited by Verein Deutscher Eisenhüttenleute (VDEh). Düsseldorf: Verlag Stahleisen, 1995, 616 p.
Review
For citations:
Lykasov A.A., Ryss G.M., Sharafutdinov D.G., Pogodin A.Yu. RECOVERY OF IRON FROM WASTE SLAG OF COPPER INDUSTRY. Izvestiya. Ferrous Metallurgy. 2016;59(9):597-607. (In Russ.) https://doi.org/10.17073/0368-0797-2016-9-597-607