PHYSICAL AND CHEMICAL ANALYSIS OF PRACTICE MODIFYING ABILITY OF BARIUM-STRONTIUM CARBONATE BSK-2 IN CAST IRON MANUFACTURING
https://doi.org/10.17073/0368-0797-2015-10-749-755
Abstract
The absence of unambiguous interpretation of experimental data
on the modifi cation of metals and alloys makes it relevant to search and prove hypotheses beyond the classical physical and chemical approach. The paper presents a quantum-mechanical theory of modifying infl uence of substances, in particular the oxides BaO, SrO, CaO in the composition of natural modifi er BSK-2 to metal properties, to complement the classical theory of heterogeneous nucleation of solids. The uniform nature of the modifying infl uence of substances, vibration and ultrasound on the molten metal is connected with the occurrence of the Friedel oscillations. The physics of the contact potential difference shows characteristics of the nucleation process in metal melts. The modifying ability of ultrafi ne inclusions is explained by the theory
of free electrons.
About the Authors
I. F. SelyaninRussian Federation
Dr. Sci. (Eng.), Professor of the Chair “Materials, foundry and welding production”
A. V. Feoktistov
Russian Federation
Cand. Sci. (Eng.), Vice-Rector
V. B. Deev
Russian Federation
Dr. Sci. (Eng.), Professor, Deputy Head of Chair “Technology of foundry processes”
O. G. Modzelevskaya
Russian Federation
Senior Lecturer of the Chair of Quality Management
A. A. Kutsenko
Russian Federation
Cand. Sci. (Eng.), Engineer of the first cate gory of the Department of scientifi c research
References
1. Ryabchikov I.V., Mizin V.G., Andreev V.V. Kremnistye ferrosplavy i modifi katory novogo pokoleniya. Proizvodstvo i primenenie [Siliceous ferroalloys and modifi ers of a new generation. Production and usage]. Chelyabinsk: Izd-vo ChGU, 2013. 295 p. (In Russ.).
2. Panov, A.G., Panfi lov E.V., Gurtovoi D.A. Quality management of cast iron of ark melting for high-ranking automotive castings. Liteinoe proizvodstvo. 2011, no. 12, pp. 5‒7. (In Russ.).
3. Panov, A.G., Chernyavskii M.S., Pimnev D.U., Kornienko A.B. Crystallization management of cast iron of cupola heat when producing mould casting. Liteishchik Rossii. 2011, no. 6, pp. 25‒27. (In Russ.).
4. Modzelevskaya O.G., Kiselev E.A., Feoktistov A.V. etc. Casting of baths made of cast iron, modifi ed with Ba-Sr-carbonate. Liteinoe proizvodstvo. 2015, no. 6, pp. 6‒8. (In Russ.).
5. Rebinder P.A. Modifi cation of metals. Fine steel. 1939, no. 3, pp. 31–34. (In Russ.).
6. Mal’tsev M.V. Modifi tsirovanie struktury metallov i splavov [Structure modifi cation of metals and alloys]. Moskow: Metallurgiya, 1964. 282 p. (In Russ.)
7. Vertman A.A., Samarin A.M. Svoistva rasplavov zheleza [Properties of iron melts]. Moscow: Nauka, 1969. 262 p. (In Russ.).
8. Khamitov R.M. Kompleksnoe issledovanie vliyaniya vibratsii na svoistva serogo chuguna s tsel’yu polucheniya germetichnykh otlivok: avtoref. diss. kand. teh. nauk [Complex research of vibration influence on the properties of grey cast iron in order to obtain hermetic castings. Extended Abstract of Cand. Sci. Diss.]. Novokuznetsk. 2004. 17 p. (In Russ.).
9. Tiler W.A., Takahashi T. Acta metallurgica, 1969, Vol. 17, no. 4, pp. 114–121.
10. Khrapov A.Ya., Selyanin I.F. On the mechanism of cast iron graphitization from the point of energy-band theory. Izvestiya VUZov. Chernaya metallurgiya = Izvestiya. Ferrous Metallurgy. 1968, no. 2, pp. 132–133. (In Russ.).
11. Selyanin I.F., Deev V.B., Kutsenko A.I., Kutsenko A.A., Kozyrev N.A. Infl uence of contact potential difference on the nucleation in metal melts. Liteishсhik Rossii. 2012, no. 10, pp. 22–23. (In Russ.).
12. Flemings Merton C. Soliifi cation processing, McGraw-Hill, 1974, 364 p. (Russ.ed.: Flemings M. Protsessy zatverdevaniya. Moscow: Mir, 1977. 423 p.).
13. Fomenko V.S., Podchernyaeva I.A. Emissionnye i adsorbtsionnye svoistva veshсhestv i materialov [Emissive and adsorption properties of substances and materials]. Moscow: Atomizdat, 1976. 320 p. (In Russ.).
14. Pimnev D.Yu., Chernyavskii M.S., Fisakova O.N. etc. Usage of barium-strontium modifi er BSK-2 for the treatment of heat-resistant steel. Liteishсhik Rossii. 2012, no. 1, pp. 31–33. (In Russ.).
15. Kuznetsov V.A. Vliyanie ul’tradispersnyсh poroshkov tugoplavkikh materialov na svoistva litykh izdelii iz chernykh i cvetnykh metallov i splavov: avtoref. diss. kand. teh. nauk [Infl uence of superdispersed powders of heat-resistant materials on the properties of castings from ferrous and non-ferrous metals and alloys: Extended Abstract of Cand. Sci. Diss]. Krasnoyarsk, 2013. 145 p. (In Russ.).
16. Harrison Walter A. Solid state theory. McGraw-Hill, New York,1970, 554 p. (Russ.ed.: Harrison W. Teoriya tverdogo tela. Moscow: Mir, 1972. 616 р.).
Review
For citations:
Selyanin I.F., Feoktistov A.V., Deev V.B., Modzelevskaya O.G., Kutsenko A.A. PHYSICAL AND CHEMICAL ANALYSIS OF PRACTICE MODIFYING ABILITY OF BARIUM-STRONTIUM CARBONATE BSK-2 IN CAST IRON MANUFACTURING. Izvestiya. Ferrous Metallurgy. 2015;58(10):749-755. (In Russ.) https://doi.org/10.17073/0368-0797-2015-10-749-755