Preview

Izvestiya. Ferrous Metallurgy

Advanced search

FORMATION OF TIN INCLUSIONS IN STEEL MELTS – THERMODYNAMIC CALCULATIONS BASED ON THE VERIFIED DATA

https://doi.org/10.17073/0368-0797-2015-6-439-443

Abstract

Using the new, verified by the authors earlier reference data after additional check of their adequacy thermodynamic conditions of formation of inclusions of TiN in steel melts Cr18Ni12T (18/12) and Cr20Ni20T (20/20) types were calculated. Conditions of decrease in impurity specified melts by congestions of TiN were defined. For simplification of calculations the public interactive site is created. For the melt of 20/20 conditions of formation of TiN were calculated also by means of known Thermo-Calc system. The values of TiN solubilities received thus considerably exceed results of the calculations stated above which are compatible with known experimental data. These divergences are connected generally with verification of titan activity coefficients in melts on the iron base which in Thermo-Calc system are not considered yet. The authors have given the recommendations about the use of the research results on practice.

About the Authors

E. V. Lysenkova
National University of Science and Technology “MISIS”
Russian Federation
Assistant of the Chair “Metallurgy of steel and ferroalloys” dy>


A. Ya. Stomakhin
National University of Science and Technology “MISIS”
Russian Federation
Dr.Sci. (Eng.), Professor of the Chair “Metallurgy of steel and ferroalloys”


References

1. Samsonova M.A., Kostina M.V., Blinov V.M. The structure and properties of the nitrogen-containing heat resistant austenitic steels after test duration for 104 hours. In: sb. trudov V Mezhdunarodnoi konferentsii “Deformatsiya i razrushenie materialov i nanomaterialov” [Coll. of papers of the Vth International Conference “Deformation and Destruction of Materials and Nanomaterials”, November 26–29, 2013]. Moscow: IMET RAN, 2013, pp. 356–358. (In Russ.).

2. Blinov V.M., Kostina M.V., Blinov E.V., Khadyev M.S. Structure and properties of high-temperature austenitic low-carbon 01Kh15N22AG2V4TYu and 02Kh18N12AG11MFB steels. Russian Metallurgy (Metally). 2011, no. 9, pp. 798–812.

3. Stomakhin A.Ya., Lysenkova E.V., Kan M.Yu., Klachkov A.A., Kolesnikov V.A. Optimization of nitride forming additive elements in steel. Chernye metally, 2010 no. 2, pp. 15–19. (In Russ.).

4. Stomakhin A.Ya., Lysenkova E.V. Activity coefficient of titanium in iron-based melts under nitride formation/dissolution conditions. Russian Metallurgy (Metally). 2013, no. 11, pp. 834–839.

5. Grigoryan V.A., Belyanchikov L.N., Stomakhin A.Ya. Teore ticheskie osnovy elektrostaleplavil’nykh protsessov [Theoretical foundations of EAF process]. Moscow: Metallurgiya, 1987, 272 p. (In Russ.).

6. http://www.thermocalc.se

7. Wada H., Pehlke R.D. Nitrogen Solution and Titanium Nitride Precipitations in Liquid Fe-Cr-Ni Alloys. Met. Trans. Vol. 8B, September 1977, pp. 433–450.

8. Shahapurkar D.S. and Small W.M. Effect of Titanium on the Nitrogen Solubility in Complex Liquid Fe-Cr-Ni Alloys. Materials Transactions, Vol. 18B, March 1987, pp. 231–235.

9. Sigworth G.K., Elliott J.F. The Thermodynamics of Liqid Dilute Iron Alloys. Metal Science, Vol. 8, 1974, pp. 298–308.

10. Borodulin G.M., Moshkevich E.I. Nerzhaveyushchaya stal’ [Stainless steels]. Moscow: Metallurgiya, 1973, 320 p. (In Russ.).

11. Rabinovich A.V., Zaslavskii Yu.B., Milova I.M., Korostelev G.R. Development of technology for the solid-state decarburization and nitrogen doping (TOLA) of rolling products of high-chromium steels. In: Trudy 1-i Vsesoyuznoi Konferentsii «Vysokoazotistye stali». Kiev. 18-20 aprelya 1990 [Proceedings of the 1st All-Union Conference “High-Nitrogen Steels. Kiev, 1990], pp. 91–97. (In Russ.).


Review

For citations:


Lysenkova E.V., Stomakhin A.Ya. FORMATION OF TIN INCLUSIONS IN STEEL MELTS – THERMODYNAMIC CALCULATIONS BASED ON THE VERIFIED DATA. Izvestiya. Ferrous Metallurgy. 2015;58(6):439-443. (In Russ.) https://doi.org/10.17073/0368-0797-2015-6-439-443

Views: 785


Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 License.


ISSN 0368-0797 (Print)
ISSN 2410-2091 (Online)