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FEATURES BEHAVIOR OF TIN, DISSOLVED IN THE LIQUID IRON BY REACTION WITH EXOGENOUS REFRACTORY NANOPHASE

https://doi.org/10.17073/0368-0797-2014-7-16-20

Abstract

Thermodynamic option pricing nanoscale particles of refractory phases of Al2O3 and MgO were spent for their introduction into the melt model of Fe – Sn. Preparing technique of a composite material consisting of a mixture of micropowder iron and oxide nanopowders were improved with further obtain extruded composite solid-refining by introducing the composite to the melt. The authors studied the interactions of nanoparticles with a surfactant Sn and investigated hetero phase interaction Al2O3 and MgO with Sn. It was found that the degree of removal of Sn in the Fe – Sn – Al2O3 system was 17.1–22.8 rel. %, and in the Fe – Sn – MgO system – 19.8–24.6 %. It depends on the time of isothermal aging (5–20 min) and the concentration of nanoparticles in the melt (0.06–0.18 wt. %). 

About the Authors

S. N. Anuchkin
Institute of Metallurgy and Material Science named after Baykov A.A., RAS (Leninskii pr., 49, 119991, Moscow, Russia)
Russian Federation
Acting Junior Researcher


V. T. Burtsev
Institute of Metallurgy and Material Science named after Baykov A.A., RAS (Leninskii pr., 49, 119991, Moscow, Russia)
Russian Federation
Dr. Sci. (Eng.), Leading Researcher


A. V. Samokhin
Institute of Metallurgy and Material Science named after Baykov A.A., RAS (Leninskii pr., 49, 119991, Moscow, Russia)
Russian Federation

Cand. Sci. (Eng.), Senior Researcher



References

1. Anuchkin. S.N., Burtsev V.T., Samokhin A.V., Gvozdkov I.A. Infl uence of the size factors on heterophase interaction of exogenous nanoparticles of refractory compounds with sulfur in the model of nickel melt. Metally – Russian Metallurgy (Metally). 2012. No. 2, pp.11–19. (In Russ.).

2. Kuznetcov D.V., Kostitsyn M.A., Konyukvov Yu.V. Development of a procedure for modifying nanomaterials of mullitecorundum mixes in equipment with a high-intensity rotating electromagnetic fi eld. Refractories and industrial ceramics. 2012. Vol. 53. No. 1, pp. 54–58.

3. Eremin, E.N. Filippov Yu.O., Eremin A.E. Promising Method of Producing Cast Billets from. Russian Metallurgy (Metally). 2010. No. 12, pp. 1131–1135.

4. Anuchkin S.N., Burtsev V.T., Samokhin A.V. Physico-metal model of nickel and iron melts, containing surfactant and exogenous refractory nanophase. Institut metallurgii i materialovedeniya im. A.A. Baikova RAN – 75 let, Sb. nauchnykh trudov [Institute of Metal lurgy and Material Science named after Baykov A.A., RAS – 75th Anniversary, References], Moscow: Interkontakt Nauka, 2013, pp. 73–94. (In Russ.).

5. Zaitsev A.I., Zaitseva N.E., Shakhpazov E.Kh., Mogutnov B.M. Thermodynamic characteristics of evaporation of liquid iron alloys with tin. Zhurnal fi zicheskoi khimii – Russian Journal of Physical Chemistry (A). 2002. Vol. 76. No.12, pp. 2129–2136. (In Russ.).

6. Nogi K., Chung W.B., McLean A. etc. Surface tension of liquid Fe – (Cu, Sn, Cr) and Ni – (Cu, Sn) binary alloys. Materials Transactions JIM. 1991. Vol. 32. No. 2, pp. 164–168.

7. Buzek. Z. Fundamental Thermodynamic Data on Metallurgical Reactions and Interactions of Elements in System Signifi cant for Metallurgical Theory and Practice. Ostrava: Vyzkumny ustav hutnictvi zeleza. 1979. 110 p.

8. Turkdogan E.T. Fizicheskaya khimiya vysokotemperaturnykh protsessov [Physical chemistry of high temperature processes]. Moscow: Metallurgiya, 1985. 344 p. (In Russ.).

9. Naidich Yu.B. Kontaktnye yavleniya v metallicheskikh rasplavakh [Contact phenomena in metallic melts]. Kiev: Naukova dumka, 1972. 196 p. (In Russ.).

10. Tsvetkov Yu.V. Samokhin A.V. Plasma Nanopowder Metallurgy. Avtomaticheskaya svarka. 2008. No. 11, pp. 171–175. (In Russ.).

11. Anuchkin. S.N., Gvozdkov I.A., Samokhin A.V., Serov G.V., Burtsev V.T. Properties of composite nanomaterial Al2O3 / Ni, obtained by mechanochemistry. Fizika i khimiya obrabotki materia lov – Inorganic Materials: Applied Research. 2011. No. 2, pp. 71–78. (In Russ.).

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For citations:


Anuchkin S.N., Burtsev V.T., Samokhin A.V. FEATURES BEHAVIOR OF TIN, DISSOLVED IN THE LIQUID IRON BY REACTION WITH EXOGENOUS REFRACTORY NANOPHASE. Izvestiya. Ferrous Metallurgy. 2014;57(7):16-20. (In Russ.) https://doi.org/10.17073/0368-0797-2014-7-16-20

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ISSN 0368-0797 (Print)
ISSN 2410-2091 (Online)