Elemental and phase composition of electric arc coating formed with a flux-cored wire of Fe – C – Si – Mn – Сr – Ni – Mo system
https://doi.org/10.17073/0368-0797-2022-2-120-126
Abstract
The authors have studied the elemental and phase compositions of electric arc coating with a flux-cored wire of Fe – C – Si – Mn – Cr – Ni – Mo system. Formation of electric arc coating was carried out using ASAW-1250 welding tractor with fabricated flux-cored wire on plates made of 09G2S steel. Aluminum production gas cleaning dust has been introduced into the composition of flux cored wire (instead of amorphous carbon). Chemical composition of the deposited metal was determined by X-ray fluorescence method on XRF-1800 spectrometer and by the atomic emission method on DFS-71 spectrometer. Microstructure of the electric arc coatings was studied using OLYMPUSGX-51 optical microscope. Analysis of phase and elemental compositions was performed by scanning electron microscopy using LEO EVO 50 instrument. Segregation of tungsten and molybdenum was revealed in electric arc coating. Concentration of tungsten changes more than 3 times, and molybdenum – more than 2 times. Fractures of the samples are formed as a result of ductile fracture of the material. There are surface layers on the samples fractures, thickness of which is determined by chemical and elemental composition of the electric arc coating. The layer under consideration is characterized by a relatively small diameter of fracture pits compared to the samples volume. Their diameter ranges from tenths to tens of micrometers. The largest pits are formed on particles of the second phase with micron sizes (2 – 3 µm). Contamination of metal of electric arc coatings with nonmetallic inclusions was studied. It was established that chemical composition of flux-cored wire of the studied system does not significantly affect the level of contamination with non-metallic inclusions in electric arc coatings. Parameter a of crystal lattice and values of areas of coherent scattering of Fe and CrC phases formed as a result of hardfacing were determined by X-ray phase analysis.
About the Authors
N. A. KozyrevRussian Federation
Nikolai A. Kozyrev, Dr. Sci. (Eng.), Prof., Vice-Rector for Research and Innovation
42 Kirova Str., Novokuznetsk, Kemerovo Region – Kuzbass 654007
A. A. Usol’tsev
Russian Federation
Aleksandr A. Usol’tsev, Cand. Sci. (Eng.), Assist. Prof. of the Chair “Materials, Foundry and Welding Production”
42 Kirova Str., Novokuznetsk, Kemerovo Region – Kuzbass 654007
A. I. Gusev
Russian Federation
Aleksandr I. Gusev, Candidates for a degree of Сand. Sci. (Eng.) of the Chair “Materials, Foundry and Welding Production”
42 Kirova Str., Novokuznetsk, Kemerovo Region – Kuzbass 654007
A. R. Mikhno
Russian Federation
Aleksei R. Mikhno, Postgraduate of the Chair “Materials, Foundry and Welding Production”
42 Kirova Str., Novokuznetsk, Kemerovo Region – Kuzbass 654007
V. E. Gromov
Russian Federation
Viktor E. Gromov, Dr. Sci. (Phys.-Math.), Prof., Head of the Chair of Science named after V.M. Finkel
42 Kirova Str., Novokuznetsk, Kemerovo Region – Kuzbass 654007
References
1. Kejžar R., Grum J. Hardfacing of wearresistant deposits by MAG welding with a fluxcored wire having graphite in its filling. Welding International. 2005, vol. 20, no. 6, pp. 961–976. https://doi.org/10.1081/AMP-200060424
2. Ma H.R., Chen X.Y., Li J.W., Chang C.T., Wang G., Li H., Wang X.M., Li R.W. Febased amorphous coating with high corrosion and wear resistance. Surface Engineering. 2017, vol. 33, no. 1, pp. 56–62. https://doi.org/10.1080/02670844.2016.1176718
3. Metlitskii V.A. Fluxcored wires for arc welding and surfacing of cast iron. Welding International. 2008, vol. 22, no. 11, pp. 796–800. https://doi.org/10.1080/09507110802593646
4. Lim S.C., Gupta M., Goh Y.S., Seow K.C. Wear resistant WC–Co composite hard coatings. Surface Engineering. 1997, vol. 13, no. 3, pp. 247–250. https://doi.org/10.1179/sur.1997.13.3.247
5. Liu D.S., Liu R.P., Wei Y.H. Influence of tungsten on microstructure and wear resistance of iron base hardfacing alloy. Materials Science and Technology. 2013, vol. 30, no. 3, pp. 316–322. https://doi.org/10.1179/1743284713Y.0000000359
6. Deng X.T., Fu T.L., Wang Z.D., Misra R.D.K., Wang G.D. Epsilon carbide precipitation and wear behaviour of low alloy wear resistant steels. Materials Science and Technology. 2016, vol. 32, no. 4, pp. 320–327. https://doi.org/10.1080/02670836.2015.1137410
7. Li R., He D.Y., Zhou Z., Wang Z.J., Song X.Y. Wear and high temperature oxidation behaviour of wire arc sprayed iron based coatings. Surface Engineering. 2014, vol. 30, no. 11, pp. 784–790. https://doi.org/10.1179/1743294414Y.0000000331
8. Filippov M.A., Shumyakov V.I., Balin S.A., Zhilin A.S., Lehchilo V.V., Rimer G.A. Structure and wear resistance of deposited alloys based on metastable chromium–carbon austenite. Welding International. 2015, vol. 29, no. 10, pp. 819–822. https://doi.org/10.1080/09507116.2014.986891
9. Zhuk Yu. Superhard wearresistant coating systems. Materials Technology. 1999, vol. 14, no. 3, pp. 126–129. https://doi.org/10.1080/10667857.1999.11752827
10. Hardell J., Yousfi A., Lund M., Pelcastre L., Prakash B. Abrasive wear behaviour of hardened high strength boron steel. Tribology – Materials, Surfaces & Interfaces. 2014, vol. 8, no. 2, pp. 90–97. https://doi.org/10.1179/1751584X14Y.0000000068
11. Kirchgaßner M., Badisch E., Franek F. Behaviour of ironbased hardfacing alloys under abrasion and impact. Wear Journal. 2008, vol. 265, no. 56, pp. 772–779. https://doi.org/10.1016/j.wear.2008.01.004
12. Lugovaya V.A., Yaroshik V.V. Hardfacing of composite alloys at hardening of working surfaces of rotation bodies. Vestnik Volgogradskogo gosudarstvennogo arkhitekturno-stroitel’nogo universiteta. Stroitel’stvo i arkhitektura. 2015, no. 40 (59), pp. 166–173. (In Russ.).
13. Teplyashin M.V., Komkov V.G., Starienko V.A. Development of cost effectively alloy for restoration of hammer mill bits. Uchenye zametki TOGU. 2013, vol. 4, no. 4, pp. 1543–1549. (In Russ.).
14. Eremin A.E., Eremin E.N., Filippov Yu.O., Matalasova A.E., Kats V.S. Structure and properties of highchromium metal of shutoff valves deposited with massproduced welding wires. Omskii nauchnyi vestnik. 2014, no. 1 (127), pp. 55–58. (In Russ.).
15. Emelyushin A.N., Petrochenko E.V., Nefed’ev S.P. Structure and impactabrasive wear resistance of coatings of Fe–C–Cr–Mn–Si system additionally alloyed with nitrogen. Svarochnoe proizvodstvo. 2011, no. 10, pp. 18–22. (In Russ.).
16. Gusev A.I., Romanov D.A., Kozyrev N.A., Gromov V.E., Ivanov Yu.F. Structure of weld of wear resistant hardfacing with a fluxcored wire of Fe – C – Si – Mn – Cr – Ni – Mo system. Vestnik Sibirskogo gosudarstvennogo industrial’nogo universiteta. 2021, no. 2 (36), pp. 3–11. (In Russ.).
17. Vostretsov G.N., Bich T.A., Bashchenko L.P. Fluxcored wire for plasma hardfacing of rolling rolls in nitrogen medium. Vestnik Sibirskogo gosudarstvennogo industrial’nogo universiteta. 2014, no. 3 (9), pp. 36–40. (In Russ.).
18. Osetkovskii I.V., Kozyrev N.A., Gusev A.I., Kryukov R.E., Popova M.V. Wear resistance of metal deposited with fluxcored wires of Fe–C–Si –Mn–Ni–Mo–V and Fe–C–Si–Mn–Cr–Ni–Mo –V systems. Vestnik Sibirskogo gosudarstvennogo industrial’nogo universiteta. 2017, no. 4 (22), pp. 21–24. (In Russ.).
19. Kozyrev N.A., Gusev A.I., Galevskii G.V., Kryukov R.E., Osetkovskii I.V., Usol’tsev A.A., Kozyreva O.A. Flux-cored wire. Patent RF no. 2641590. МПК8 B23 К35/36 В 23 К35/36. Bulleten’ izobretenii. 2018, no. 2. (In Russ.).
20. Gusev A.I., Kozyrev N.A., Kibko N.V., Popova M.V., Osetkovskii I.V. Properties of fluxcored wire of Fe –C–Si–Mn –Cr– –Mo–Ni–V–Co system for hardening of nodes and parts of equipment of mining and coal mining industries. Naukoemkie tekhnologii razrabotki i ispol’zovaniya mineral’nykh resursov. 2017, no. 3, pp. 135–140. (In Russ.).
Review
For citations:
Kozyrev N.A., Usol’tsev A.A., Gusev A.I., Mikhno A.R., Gromov V.E. Elemental and phase composition of electric arc coating formed with a flux-cored wire of Fe – C – Si – Mn – Сr – Ni – Mo system. Izvestiya. Ferrous Metallurgy. 2022;65(2):120-126. (In Russ.) https://doi.org/10.17073/0368-0797-2022-2-120-126