Preview

Izvestiya. Ferrous Metallurgy

Advanced search

Surface hardening of carbide tools based on tungsten carbide by concentrated energy flows

https://doi.org/10.17073/0368-0797-2021-12-870-876

Abstract

The article presents the results of surface hardening of tungsten­carbide hard alloys carried out using concentrated energy flows. The VK6­OM alloy with a thickness of 20 μm is applied to the hard alloy VK10KS by the method of electric spark treatment. In this case, a surface hardened layer consisting of W2C is obtained. The hardness of the resulting layer is 22,000 MPa and the friction coefficient is 0.23 (compared to the friction coefficient of the original hard alloy of 0.41); strong but insufficiently wear­resistant base is preserved. In the work, a surface layer on a hard alloy VK10KS with a thickness of 40 μm and phase composition of TiC and W2C was obtained by the method of single­component electro­explosive alloying with titanium. The nanohardness of this layer is 25,000 MPa and the friction coefficient is 0.14. A surface layer with thickness of 3 – 4 μm and phase composition of TiB2 , TiC, W2C was obtained on the hard alloy VK10KS by the method of multicomponent electro­explosive alloying with titanium and boron. The nanohardness of the hardened layer is 27,500 MPa and the friction coefficient is 0.10. Applying the technique of separate cathodes, an ion­plasma TiN + ZrN coating (50 % Ti + 50 % Zr) with a thickness of 20 μm was applied to the surface of the VK10KS hard alloy. Nitrogen was used as the reaction gas. The nanohardness of the surface layer hardened in this way is 38,500 MPa and the friction coefficient of is 0.07. Ion­plasma TiN + ZrN coating has good adhesion to the substrate. The use of the proposed methods of surface hardening of VK10KS hard alloy makes it possible to choose one of the hardening methods, based on operating conditions of the carbide tool, to extend its operational life, as well as to save scarce materials (tungsten and cobalt).

About the Authors

T. N. Oskolkova
Siberian State Industrial University
Russian Federation

Tat’yana N. Oskolkova, Dr. Sci. (Eng.), Prof. of the Chair “Metal Forming and Metal Science. “EVRAZ ZSMK”

42 Kirova Str., Novokuznetsk, Kemerovo Region – Kuzbass 654007



A. M. Glezer
National University of Science and Technology “MISIS” (MISIS); I.P. Bardin Central Research Institute for Ferrous Metallurgy
Russian Federation

Aleksandr M. Glezer, Dr. Sci. (Eng.), Prof., Chief Researcher; Director of the Scientific Center “Metal Science and Physics of Materials”

4 Leninskii Ave., Moscow 119049

23/9, bld. 2 Radio Str., Moscow 105005



A. S. Simachev
Siberian State Industrial University
Russian Federation

Artem S. Simachev, Cand. Sci. (Eng.), Assist. Prof. of the Chair “Metal Forming and Metal Science. “EVRAZ ZSMK”

42 Kirova Str., Novokuznetsk, Kemerovo Region – Kuzbass 654007



References

1. Tabakov V.P. Formation of Wear­Resistant Ion­Plasma Coatings of Cutting Tools. Moscow: Mashinostroenie, 2008, 311 p. (In Russ.).

2. Bogodukhov S.I., Kozik E.S., Svidenko E.V. Hardening of hard alloys (Review). Uprochnyayushchie tekhnologii i pokrytiya. 2015, vol. 131, no. 11, pp. 3–1. (In Russ.).

3. Ivanov A.N., Khmelevskaya V.S., Antoshina I.A., Korshunov A.B. Structural changes in hard alloy VK8 under ion irradiation. Perspektivnye materialy. 2003, no. 1, pp. 89–92. (In Russ.).

4. Petrenko P.V., Grabovskii Yu.E., Gritskevich A.L., Kulish N.P. Structural­phase transformations in WC–Co hard alloys under irradiation with a low-current electron beam. Fizika i khimiya obrabotki materialov. 2003, no. 3, pp. 29–39. (In Russ.).

5. Timoshnikov Yu.A., Klopotov A.A., Ivanov Yu.F. Variation of structure­phase state of VK8 alloy under action of gamma quanta. Izvestiya. Ferrous Metallurgy. 2001, no. 4, pp. 40–43. (In Russ.).

6. Liu S.R., Hao J.M., Chu L.G., Song J.T. Mechanism of hard­facing alloys WC­Co boronizing with rare­earth metals. Xiyou Jinshu Cai­ liao Yu Gongcheng. Rare Metal Materials and Engineering. 2003, vol. 32, no. 4, pp. 305–308.

7. Liu S.R., Hao J.M., Chu L.G., Song J.T. Phase analysis of cemented carbide WC–Co boronised with yttrium. Journal of Rare Earths. 2002, vol. 40, no. 4, pp. 287–290.

8. Liu Y., Vid Q., Li Y. Synthesis and tribological behavior of electroless Ni–P–WC nanocomposite coatings. Surface & Coatings Technology. 2007, vol. 201, no. 16–17, pp. 7246–7251. https://doi.org/10.1016/j.surfcoat.2007.01.035

9. Veprek S., Veprek­Hejman M.G.J., Kavrankova P., Prohazka J. Different approaches to superhard coatings and nanocomposition. Thin Solid Films. 2005, vol. 476, pp. 1–29. https://doi.org/10.1016/j.tsf.2004.10.053

10. Jedrzejowski P., Klemberg­Sapieha J.E., Martinu L. Relationship between the mechanical properties and the microstructure of nanocomposite, TiN/SiNi3 coatings prepared by low temperature plasma enhanced chemical vapor deposition. Thin Solid Films. 2003, vol. 426, pp. 150–159. https://doi.org/10.1016/S0040-6090(03)00028-2

11. Mayrhofer P.H., Kunc F., Musil J., Mitterer C. A comparative study on reactive and non-reactive unbalanced magnetron sputter deposition of TiN coatings. Thin Solid Films. 2002, vol. 415, no. 1­2, pp. 151–159. https://doi.org/10.1016/S0040-6090(02)00511-4

12. Oskolkova T.N. A new technology for producing carbide alloys with gradient structure. IOP Conference Series: Materials Science and Engineering. 2015, vol. 91, no. 1, article 012019. https://doi.org/10.1088/1757-899X/91/1/012019

13. Tyurin Yu.N., Kul’kov S.N., Kolisnichenko O.V., Duda I.M. Pulsed plasma modification of the surface of a WC + 20 % Co alloy pro­ duct. Fizicheskaya inzheneriya poverkhnosti. 2009, vol. 7, no. 3, pp. 262–267. (In Russ.).

14. Oskolkova T.N., Budovskikh E.A., Goryushkin V.F. Features of structure formation of the surface layer in the course of electroexplosive alloying tungsten carbide hard alloy. Russian Journal of Non­Ferrous Metals. 2014, vol. 55, no. 2, pp. 196–200. https://doi.org/10.3103/S1067821214020138

15. Oskolkova T.N., Glezer A.M. Wear­resistant coatings on WC–Co hard alloys synthesized by concentrated energy flows. Inorganic Materials: Applied Research. 2019, vol. 10, no. 1, pp. 146–154. https://doi.org/10.1134/S2075113319010258

16. Oskolkova T.N., Budovskikh E.A. Pulse plasma treatment of the surface of alloy VK10KS. Metal Science and Heat Treatment. 2012, vol. 53, no. 11–12, pp. 608–610. https://doi.org/10.1007/s11041-012-9443-1

17. Panov V.S., Chuvilin A.M., Fal’kovskii V.A. Technology and Pro­ perties of Special Hard Alloys and Products from Them. Moscow: MISiS, 2004, 464 p. (In Russ.).

18. Vereshchaka A.S., Vereshchaka A.A. Improving the tool efficiency by controlling the composition, structure and properties of coatings. Uprochnyayushchie tekhnologii i pokrytiya. 2005, no. 9, pp. 9–18. (In Russ.).

19. Yatsenko A.S., Marchuk S.I. Study of corrosion resistance of hard alloys coated with titanium nitride. In: Metal Science of Ferrous and Non­Ferrous Alloys. Transactions. Issue 9. Donetsk: Donetskii nats. tekhn. un­t, 2003, pp. 29–33. (In Russ.).

20. Tabakov V.P., Tsirkin A.V., Chikhranov A.V. Cutting tool with multilayer coating. Patent RF no. 2270270. Bulleten’ izobretenii. 2006, no. 5. (In Russ.).


Review

For citations:


Oskolkova T.N., Glezer A.M., Simachev A.S. Surface hardening of carbide tools based on tungsten carbide by concentrated energy flows. Izvestiya. Ferrous Metallurgy. 2021;64(12):870-876. (In Russ.) https://doi.org/10.17073/0368-0797-2021-12-870-876

Views: 441


Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 License.


ISSN 0368-0797 (Print)
ISSN 2410-2091 (Online)