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Control of oxide non-metallic inclusions in production of IF steel

https://doi.org/10.17073/0368-0797-2020-10-782-790

Abstract

Modern trends in the automotive industry are aimed at reducing vehicle weight and increasing its safety. The high ductility of IF-BH steel in combination with increased strength allows the use of thinner rolled products in the car body structure. Achievement of high plastic properties in IF-BH steel is ensured by the low content of nitrogen and carbon (C <40 ppm, N <40 ppm) and controlled carbon content in the solid solution. The majority of sheet surface defects are associated with non-metallic inclusions. The presence of non-metallic inclusions in the finished product violates its homogeneity, deteriorates the surface properties of steel, fatigue strength and plastic characteristics of the metal. As a result of the work performed by the methods of fractional gas and micro-X-ray spectral analysis on a scanning electron microscope, metal samples of three IF-BH steel melts were analyzed, taken along the entire process chain of production. The main types of oxide non-metallic inclusions in the steel were quantitatively determined, as well as the total oxygen and nitrogen content in the metal. It is shown that the main types of oxide non-metallic inclusions in the investigated metal samples are aluminates, silicates and spinel. An increase in nitrogen content in the metal after breakdown of the vacuum on the VD was established, which indicates secondary oxidation of the metal. In metal of the samples in the section between the tundish and the crystallizer, nitrogen content in the metal increases which indicates the secondary metal oxidation. At the same time, the content of inclusions of aluminates in the metal increased and the number of inclusions of aluminum-magnesium spinel decreased. A mathematical model and software have been developed that describe the formation and removal of oxide nonmetallic inclusions. Adequacy of the program was confirmed by good convergence between the calculated and laboratory data on the total content [O] in various types of oxides for the first sample at the ladle-furnace unit and in the slab.

About the Authors

A. O. Morozov
National University of Science and Technology “MISIS” (MISIS); Baikov Institute of Metallurgy and Materials Science, RAS
Russian Federation

Research Engineer of the Laboratory of Materials Diagnostics

Moscow



A. M. Pogodin
National University of Science and Technology “MISIS” (MISIS); Baikov Institute of Metallurgy and Materials Science, RAS
Russian Federation

Junior Researcher of the Laboratory of Materials Diagnostics

Moscow



O. A. Komolova
National University of Science and Technology “MISIS” (MISIS); Baikov Institute of Metallurgy and Materials Science, RAS
Russian Federation

Cand. Sci. (Eng.), Assist. Professor of the Chair of Metallurgy of Steel, New Production Technologies and Metal Protection, Senior Researcher of the Laboratory of Materials Diagnostics

Moscow

 


K. B. Bikin
JSC “Severstal”, Cherepovets
Russian Federation

Leading Expert

Vologda Region



K. V. Grigorovich
National University of Science and Technology “MISIS” (MISIS); Baikov Institute of Metallurgy and Materials Science, RAS
Russian Federation

Academician, Dr. Sci. (Eng.), Professor of the Chair of Metallurgy of Steel, New Production Technologies and Metal Protection, Head of the Laboratory of Materials Diagnostics

Moscow



References

1. Bkhattashariya D. Prospects for the development of high-strength IF-steels. In: Mezhdunarodnyi seminar “Sovremennye dostizheniya v metallurgii i tekhnologii proizvodstva stalei dlya avtomobil’noi promyshlennosti”, 17 – 18 fevralya 2004 [Int. Seminar “Modern developments in metallurgy and technologies of steels for automotive industry”, 17 – 18 February, 2004]. Moscow: Metallurgizdat, 2004, pp. 71–82. (In Russ.).

2. Rodionova I., Filippov G. Technological aspects of the production of steel for automotive industry. Natsional’naya metallurgiya. 2004, no. 2, pp. 93–97. (In Russ.).

3. Titov V. Rolled steel for automotive industry. Natsional’naya metallurgiya. 2004, no. 5, pp 84–89. (In Russ.).

4. Pampa Ghosh, Chiradeep Ghosh, Ray R.K. Precipitation in interstitial free high strength steels. ISIJ International. 2009, vol. 49, no. 7, pp. 1080–1086.

5. Gorkusha D.V., Komolova O.A., Grigorovich K.V., Alpatov A.V., Arsenkin A.M. Criteria for achieving the BH effect in ultra-low carbon steels for deep drawing. Izvestiya. Ferrous Metallurgy. 2020, vol. 63, no. 3-4, pp. 201–210. (In Russ.).

6. Myung-Duk Seo, Jung-Wook Cho, Kwang-Chun Kim, Seon-Hyo Kim. Evolution of non-metallic inclusions in ultra low carbon steel after aluminum deoxidization. ISIJ International. 2014, vol. 54, no. 3, pp. 475–481.

7. Zaitsev A.I., Rodionova I.G., Khoroshilov A.D., Mezin F.I., Semernin G.V., Mishnev P.A., Zhironkin M.V., Bikin K.B. Analysis of surface defects occurrence in cold-rolled products from IF-steels. Elektrometallurgiya. 2012, no. 7, pp. 36–40. (In Russ.).

8. Zhou Xiaolei, Shi Zhe, Zhang Guifang. The evolution of non-metallic inclusions in IF steel. Applied Mechanics and Materials. 2015, vol. 696, pp. 62–65.

9. Shiozawa K, Lu L. Effect of non-metallic inclusion size and residual stresses on gigacycle fatigue properties in high strength steel. Advanced Materials Research. 2008, vol. 44–46, pp. 33–42.

10. Bate P.S. Texture development in the cold rolling of IF steel. Materials Science and Engineering: A. 2004, vol. 38, no. 1, pp. 365–377.

11. Jin Ma, Bo Zhang, Daokui Xu, En-Hou Han, Wei Ke. Effects of inclusion and loading direction on the fatigue behavior of hot rolled low carbon steel. Int. Journal of Fatigue. 2010, vol. 32, pp. 1116–1125.

12. Jouni Ikäheimonen, Kauko Leiviskä, Jari Ruuska, Jarkko Matkala. Nozzle clogging prediction in continuous casting of steel. In: 15th Triennial World Congress, July 21 – 26, 2002, Barcelona, Spain, pp. 143–147.

13. Tehovnik F., Burja J., Arh B., Knap M. Submerged entry nozzle clogging during continuous casting of al-killed steel. Metalurgija. 2015, vol. 54, no. 2, pp. 371–374.

14. Shchukina L.I., Tuvaev V.F., Komolova O.A., Grigorovich K.V. Investigation of the causes of reduced spillability of sheet steel аt domestic enterprises. In: Sbornik trudov: XV Mezhdunarodnyi kongress staleplavil’shchikov [Proceedings of XV Int. Congress of Steelmakers]. 2018, pp. 357–362. (In Russ.).

15. Karasev A.V., Suito H. Analysis of size distributions of primary oxide inclusions in Fe-10 mass pct Ni-M (M = Si, Ti, Al, Zr, and Ce) alloy. Metallurgical and Materials Transactions B. 1999, vol. 30, no. 2, pp. 259–270.

16. Ohta H., Suito H. Characteristics of particle size distribution of deoxidation products with Mg, Zr, Al, Ca, Si/Mn and Mg/Al in Fe10 mass % Ni alloy. ISIJ International. 2006, vol. 46, no. 1, pp. 14–21.

17. Kanbe Y., Karasev A., Todoroki H., Jönsson P.G. Application of extreme value analysis for two- and three-dimensional determinations of the largest inclusion in metal samples. ISIJ International. 2011, vol. 51, no. 4, pp. 593–602.

18. Manish Marotrao Pande, Muxing Guo. Determination of steel cleanliness in ultra low carbon steel by pulse discrimination analysis optical emission spectroscopy technique. ISIJ International. 2011, vol. 51, no. 11, pp. 1778–1787.

19. Gorkusha D.V., Grigorovich K.V., Karasev A.V., Komolova O.A. Content modification of different types of non-metallic inclusions during low-carbon IF steel ladle treatment. Izvestiya. Ferrous Metallurgy. 2019, vol. 62, no. 5, pp. 345–352. (In Russ.).

20. Komolova O.A., Grigorovich K.V. Mathematical models, algorithms and software for dynamic simulation of leadle treatment technology. Metallurgia Italiana. 2019, no. 3, pp. 20-24

21. Mapelli C., Barella S., Gruttadauria A., Mombelli D. Prevision of inclusional content in structural steel. In: 5th Int. Congress on the Science and Technology of Steelmaking 2012, Dresden, Germany. 2012, pp. 1–9.

22. Seshadri V., Antônio da Silva C., Alves da Silva I. A physical modelling study of inclusion removal in tundish using inert gas curtain. Tecnologia. Metalurgia, Materiais e Mineracao. 2012, vol. 9, no. 1, pp. 22–29

23. Zhang L., Thomas B.G., Wang X., Cai K. Evaluation and control of steel cleanliness – review. In: 85th Steelmaking Conference Proceedings, ISS-AIME, Warrendale, PA, 2002, pp. 431–452.

24. Lifeng Zhang. Fluid flow and inclusion removal in molten steel continuous casting strands. In: 5th Int. Conference on CFD in the Process Industries CSIRO, Melbourne, Australia, 2006, pp. 1–9.

25. Pérez J. Inclusion Control Model in Ladle Metallurgy Furnace: Mc- Master University, Master’s thesis, Ontario, 2012, p. 131.

26. Grigorovich K.V., Komolova O.A. Mathematical modeling and optimization of steelmaking technologies. In: Proceedings of the 7th Int. Congress on the Science and Technology of Steelmaking (ICS2018), 2018, Venice, Italy.


Review

For citations:


Morozov A.O., Pogodin A.M., Komolova O.A., Bikin K.B., Grigorovich K.V. Control of oxide non-metallic inclusions in production of IF steel. Izvestiya. Ferrous Metallurgy. 2020;63(10):782-790. (In Russ.) https://doi.org/10.17073/0368-0797-2020-10-782-790

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ISSN 0368-0797 (Print)
ISSN 2410-2091 (Online)