Preview

Izvestiya. Ferrous Metallurgy

Advanced search

Use of barium-strontium modifier for the manufacturing of welding flux based on silicomanganese slag

https://doi.org/10.17073/0368-0797-2020-9-686-692

Abstract

The possibility of using a barium-strontium modifier as a gasprotective and refining additive for welding the fluxes based on crushed slag from the production of ferrosilicomanganese is presented. The barium-strontium modifier BSK-2 produced by JSC “NPK Metalltekhnoprom” according to TU 1717-001-75073896–2005 was used as a material for the study. The base of the welding flux was silicomanganese slag produced by the West Siberian Electrometallurgical Plant. The research work on new welding fluxes and flux-additives was carried out using the equipment of the Scientific and Production Center “Welding Processes and Technologies” and the Center for Collective Use “Materials Science”. The use of barium-strontium flux additive was carried out in two ways. In the first option, the flux-additive was made by grinding barium-strontium to a dust-like fraction of less than 0.2 mm with further mixing with liquid sodium glass, drying in a furnace, crushing and separating a fraction of 0.45 – 3.00 mm. In the second option, the flux additive was used in the form of dust with a fraction of less than 0.2 mm. The additives were mixed at a ratio of 2 – 10 % of mass of the slag produced by silicomanganese. Surfacing of the samples was carried out with a welding wire of the sv-08GA grade on a substrate of steel grade 09G2S with a thickness of 20 mm. Quality of the deposited metal was studied, the chemical compositions (deposited layers, slag crusts, the used flux) were investigated by X-ray fluorescence method on XRF-1800 spectrometer and by atomic emission method on DFS-71 spectrometer. The degree of contamination with non-metallic inclusions (non-deforming silicates, point oxides, sulfides) was studied using OLYMPUS GX-51 optical microscope in the magnification range from 100 to 1000. The laboratory studies on the surfacing of steel samples have shown that due to introduction of a flux additive made from barium-strontium modifier, the metal is refined, and the concentration of sulfur and phosphorus decreases. The use of a mixture of a barium-strontium modifier with liquid glass as an additive is preferable to the use of an additive in the form of a dust. It was revealed that the best samples from the point of view of the degree of contamination of the deposited metal with nonmetallic inclusions are samples made using no more than 8 % of barium-strontium flux additive.

About the Authors

N. A. Kozyrev
Siberian State Industrial University
Russian Federation

Dr. Sci. (Eng.), Professor, Head of the Chair “Materials, Foundry and Welding Production”

Novokuznetsk, Kemerovo Region



R. E. Kryukov
Siberian State Industrial University
Russian Federation

Cand. Sci. (Eng.), Assist. Professor of the Chair “Materials, Foundry and Welding Production”

Novokuznetsk, Kemerovo Region



A. R. Mikhno
Siberian State Industrial University
Russian Federation

Postgraduate of the Chair “Materials, Foundry and Welding Production”

Novokuznetsk, Kemerovo Region



N. V. Kibko
Siberian State Industrial University
Russian Federation

Cand. Sci. (Eng.), Assist. Professor of the Chair “Materials, Foundry and Welding Production”

Novokuznetsk, Kemerovo Region



A. A. Usol’tsev
Siberian State Industrial University
Russian Federation

Cand. Sci. (Eng.), Assist. Professor of the Chair “Materials, Foundry and Welding Production”

Novokuznetsk, Kemerovo Region



References

1. Deryabin A.A., Berestov E.Yu. On mechanism of steel modification with alkaline earth metals. Elektrometallurgiya. 2008, no. 6, pp. 35–38. (In Russ.).

2. Deryabin A.A., Pavlov V.V., Mogil’nyi V.V., Godik L.A., Tsepelev V.S., Konashkov V.V., Gorkavenko V.V., Berestov E.Yu. Nanomodification of Rail Steel with Barium. Steel in Translation. 2007, vol. 37, no. 11, pp. 966–973.

3. Grigor’ev Yu.V., Ryabchikov I.V., Roshchin V.E. Thermodynamic analysis of joint reduction of silicon and barium by carbon. Izvestiya. Ferrous Metallurgy. 2005, no. 7, pp. 3–5. (In Russ.).

4. Ryabchikov I.V., Mizin V.G., Lyakishev N.P., Dubrovin A.S. Ferrosplavy s redkozemel’nymi i shchelochnozemel’nymi metallami [Ferroalloys with rare earth and alkaline earth metals]. Moscow: Metallurgiya, 1983, 272 p. (In Russ.).

5. Rozhikhina I.D., Nokhrina O.I., Dmitrienko V.I., Platonov M.A. Modification of steel by barium and strontium. Izvestiya. Ferrous Metallurgy. 2015, vol. 58, no. 10, pp. 871–875. (In Russ.).

6. Ivakin V.JI., Chernyak S.S., Pimnev D.Yu. Novaya tekhnologiya povysheniya kachestva metallov i splavov bariistrontsievym karbonatom [New technology for improving the quality of metals and alloys with barium strontium carbonate]. Irkutsk: izd. Irkutskogo gos. universiteta, 2004, 123 p. (In Russ.).

7. Kartashev M.F., Naumov S.V., Urchenko A.N., Sheksheev M.A. Study of welding properties of fused weld flux produced by electric arc granulation. IOP Conference Series: Materials Science and Engineering. 2019, vol. 511, no. 1, article 012034.

8. Gupta P., Roy J., Rai R.N., Rao A.K.P., Saha S.C. Effect of B2 O3 containing fluxes on the microstructure and mechanical properties in submerged arc welded mild steel plates. IOP Conference Series: Materials Science and Engineering. 2016, vol. 114, no. 1, article 012102.

9. Golovko V.V., Potapov N.N. Special features of agglomerated (ceramic) fluxes in welding. Welding International. 2011, vol. 25, no. 11, pp. 889–893.

10. Kartsev D.S., Zernin E.A. Use of refractory nanoparticles as a component of welding materials in welding and surfacing with coated electrodes and flux cored wires. IOP Conference Series: Materials Science and Engineering. 2016, vol. 142, no. 1, article 012008.

11. Crespo A.C., Puchol R.Q., Goncalez L.P., Sanchez L.G., Gomez Perez C.R., Cedre E.D., Mendez T.O., Pozol J.A. Obtaining a submerged arc welding flux of the MnO–SiO 2 –CaO–Al 2 O3 –CaF 2 system by fusion. Welding International. 2007, vol. 21, no. 7, pp. 502–511.

12. Volobuev Yu.S., Volobuev O.S., Parkhomenko A.G., Dobrozhela E.I., Klimenchuk O.S. Using a new general-purpose ceramic flux SFM-101 in welding of beams. Welding International. 2012, vol. 26, no. 8, pp. 649–653.

13. Volobuev Yu.S., Surkov A.V., Volobuev O.S., Kipiani P.N., Shestov D.V., Pavlov N.V., Savchenko A.I. The development and properties of a new ceramic flux used for reconditioning rolling stock components. Welding International. 2010, vol. 24, no. 4, pp. 298–300.

14. Potapov N.N., Kurlanov S.A. A criterion for evaluating the activity of fused welding fluxing. Welding International. 1987, vol. 1, no. 10, pp. 951–954.

15. Babushkin P.L., Persits V.Yu. Determination of hydrogen in the form of moisture in basic electrode coatings and fluxing materials in metallurgical production. Welding International. 1991, vol. 5, no. 9, pp. 741, 742.

16. Naumov S.V., Ignatov M.N., Sheksheev M.A. Technology of mineral raw materials granulation by electric arc for manufacturing of welding fused flux. Solid State Phenomena. 2017, vol. 265, pp. 290–295.

17. Muruev S.B., Rimkevich B.S., Butskii E.B., Sidorina T.N., Romanov P.M. Application of barium strontium carbonate in the production of ingots from tool steels R6M5 and Kh12MF. Elektrometallurgiya. 2008, no. 6, pp. 35–38. (In Russ.).

18. Nokhrina O.I., Rozhikhina I.D., Platonov M.A., Dmitrienko V.I. Recovery of barium and strontium during steel processing. Chernye metally. 2011, no. 4, pp. 29–31. (In Russ.).

19. Kozyrev N.A., Kryukov R.E., Kryukov N.E., Koval’skii I.N., Kozyreva O.E. Development of new welding fluxes and flux-additives for welding and surfacing of steel using metallurgical waste. Report 3. Flux additives for welding fluxes containing barium strontium carbonatite. Chernaya metallurgiya. Byul. in-ta “Chermetinformatsiya”. 2017, no. 6 (1410), pp. 95–98. (In Russ.).

20. Kozyrev N.A., Kryukov R.E., Burnakov M.A., Mikhno A.R., Fedotov E.E. Use of barium-strontium carbonatite in manufacture of welding fluxes based on slag of silicomanganese production. In: Metallurgiya: tekhnologii, innovatsii, kachestvo. Тrudy XX Mezhdunarodnoi nauchno-prakticheskoi konferentsii: v 2-kh ch. Ch. 1 [Metallurgy: Technology, Innovations, Quality: Proceedings of the 20 th Int. Sci. and Pract. Conference: in 2 parts, Part 1]. Novokuznetsk: ITs SibGIU, 2017, pp. 296–299. (In Russ.).


Review

For citations:


Kozyrev N.A., Kryukov R.E., Mikhno A.R., Kibko N.V., Usol’tsev A.A. Use of barium-strontium modifier for the manufacturing of welding flux based on silicomanganese slag. Izvestiya. Ferrous Metallurgy. 2020;63(9):686-692. (In Russ.) https://doi.org/10.17073/0368-0797-2020-9-686-692

Views: 483


Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 License.


ISSN 0368-0797 (Print)
ISSN 2410-2091 (Online)