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Utilization of dispersed waste of ferroalloy production on the basis of metallurgical SHS-process

https://doi.org/10.17073/0368-0797-2020-8-591-599

Abstract

A review of methods for processing dispersed waste from f loy production was performed. In ferroalloy plants there is a problem of formation and accumulation of cyclone dust (the catch product from crushing – CPC), formed during the grinding and fractionation of ferroalloys. The drawbacks of the known methods for the disposal of such dust are shown. The authors have investigated the possibility of obtaining commercial nitrided ligatures from CPC’s and substandard ferroalloy fines using the technology of self-propagating high-temperature synthesis (SHS). On the basis of the proposed “metallurgical” SHS method, a technology has been developed and the possibility of largescale production of nitrided ferrosilicon, ferrovanadium, ferrochrome and other materials has been shown, which has demand on the world market. Synthesized SHS materials are superior in quality to nitrided ferroalloys obtained by conventional furnace method, in particular, they have a lower content of oxygen, hydrogen and other impurities, and differ in better physical and mechanical properties: density, porosity, strength, and others. Based on the method of metallurgical SHS, the production of nitrided ferroalloys and composite ligatures with the possibility of processing up to 5000 ton per year of cyclone dust of ferrosilicon and other alloys was established in Russia, Magnitogorsk on the production base of scientific and technical production company LLC “STPF “Etalon”. A new approach to the practical implementation of the SHS method is developed and the possibility of using synthesis products in metallurgy is shown. The main application of these products is the use of alloying additives in smelting of a wide range of steels and alloys: transformer, rail, stainless, high-strength structural, and others. Another popular consumer of composite “metallurgical” SHS materials is the refractory production. Modification of traditional refractories used in smelting of cast iron, steel and non-ferrous metals with new composite SHS materials based on nitrides, borides, carbides and other refractory compounds can significantly increase the service life and reduce the expenses for refractories.

About the Authors

I. R. Manashev
LLC “STPF “Etalon”
Russian Federation

Cand. Sci. (Eng.), Deputy Development Director of composite materials production

Magnitogorsk, Chelyabinsk Region



T. O. Gavrilova
LLC “STPF “Etalon”
Russian Federation

Cand. Sci. (Eng.), Deputy General Director

Magnitogorsk, Chelyabinsk Region



I. M. Shatokhin
LLC “STPF “Etalon”
Russian Federation

Dr. Sci. (Eng.), General Director

Magnitogorsk, Chelyabinsk Region



M. Kh. Ziatdinov
National Research Tomsk State University
Russian Federation

Dr. Sci. (Eng.), Senior Researcher

Tomsk



L. I. Leont’ev
Institute of Metallurgy UB RAS; National University of Science and Technology “MISIS” (MISIS); Scientific Council on Metallurgy and Metal Science of Russian Academy of Sciences (Department of Chemistry and Material Sciences)
Russian Federation

Dr. Sci. (Eng.), Professor, Academician, Adviser of the Russian Academy of Sciences, Chief Researcher

Ekaterinburg
Moscow 



References

1. Gasik M.I., Lyakishev N.P., Emlin B.I. Teoriya i tekhnologiya proizvodstva ferrosplavov [Theory and technology of ferroalloy production]. Moscow: Metallurgiya, 1988, 784 p. (In Russ.).

2. Pavlov S.V., Snitko Yu.P., Plyukhin S.B. Waste and emissions from the production of ferrosilicon. Elektrometallurgiya. 2001, no. 4, pp. 22–28. (In Russ.).

3. Kanaev Yu.P., Bondarev A.A., Brylyakov V.I., Molchanov N.E., Shul’gin Yu.F., Lubyanoi D.A. Mastering remelting of ferrosilicon fines to produce pure grades of ferrosilicon and complex inoculants. Steel in Translation. 2000, vol. 30, no. 10, pp. 32–36.

4. Ziatdinov M.Kh., Shatokhin I.M., Leont’ev L.I. SHS Technology of composition ferroalloys. Part I. Metallurgical SHS process. Synthesis of ferrovanadium and ferrochromium nitrides. Izvestiya. Ferrous Metallurgy. 2018, vol. 61, no. 5, pp. 339–346. (In Russ.).

5. Merzhanov A.G., Mukas’yan A.C. Tverdoplamennoe gorenie [Solid-flame combustion]. Moscow: TORUS PRESS, 2007, 336 p. (In Russ.).

6. Merzhanov A.G. Fundamentals, achievements, and perspectives for development of solid-flame combustion. Russian Chemical Bulletin. 1997, vol. 46, no. 1, pp. 1–27.

7. Mizin V.G., Chirkov N.A., Ignat’ev V.S. etc. Ferrosplavy: Spravochnoe izdanie [Ferroalloys: Reference book]. Moscow: Metallurgiya, 1992, 415 p. (In Russ.).

8. Iwamoto S., Denki Kagaku Kogyo. Method for Treatment of Ferrosilicon Nitride. Patent no. 1461119, GB. Int. Cl. C01B21/06. Publ. 13.01.1977.

9. Lopes A.B. The influence of ferrosilicon nitride on the performance of the modern taphole mud for blast furnace. Refractories Applications and News. 2002, vol. 7, no. 5, pp. 26–30.

10. Pant P., Dahlmann P., Schlump W., Stein G. A new nitrogen alloying technique – a way to distinctly improve the properties of austenitic steel. Steel Research. 1987, vol. 58, no. 1, pp. 18–25.

11. Zakorzhevskii V.V., Borovinskaya I.P. Some regularities of α-Si 3 N 4 synthesis in a commercial SHS reactor. Int. Journal of Self-Propagating High-Temperature Synthesis. 2000, vol. 9, no. 2, pp. 171–191.

12. Mukas’yan A.S., Merzhanov A.G., Martynenko V.M., Borovinskaya I.P., Blinov M.Yu. Mechanism and principles of silicon combustion in nitrogen. Combustion, Explosion, and Shock Waves. 1986, vol. 22, no. 5, pp. 534–540.

13. Boyer S.M., Moulson A.J. A mechanism for the nitridation of Fecontaminated silicon. Journal of Materials Science. 1978, vol. 13, no. 8, pp. 1637–1646.

14. Vlasova M.V., Lavrenko V.A., Dyubova L.Yu., Gonzalez-Rodriguez J.G., Kakasey M.G. Nitriding of ferrosilicon powders. Journal of Materials Synthesis and Processing. 2001, vol. 9, no. 3, pp. 111–117.

15. Andrievski R.A. Melting point and dissociation of silicon nitride. Int. Journal of Self-Propagating High-Temperature Synthesis. 1995, vol. 4, no. 3, pp. 237–244.

16. Messier D.R., Riley F.L., Brook R.J. The α/β silicon nitride phase transformation. Journal of Material Science. 1978, vol. 13, no. 6, pp. 1199–1205.

17. Shatokhin I.M., Ziatdinov M.Kh., Manashev I.R. etc. Self-propagating high-temperature synthesis (SHS) of composite ferroalloys. CIS Iron and Steel Review. 2019, vol. 18, pp. 52–57.

18. Ziatdinov M.Kh., Shatokhin I.M., Leont’ev L.I. SHS Technology of composite ferroalloys. Part II. Synthesis of ferrosilicon nitride and ferrotitanium boride. Izvestiya. Ferrous Metallurgy, 2018. vol. 61, no. 7, pp. 527–534. (In Russ.).

19. Ziatdinov M.Kh. Chromium combustion in a nitrogen coflow. Combustion, Explosion and Shock Waves. 2016, vol. 52, no. 4, pp. 418–426.

20. Kolokol’tsev V.M., Vdovin K.N., Chernov V.P. etc. Investigation of mechanical and operational properties of high-manganese steel alloyed with nitrided ferrochrome. Vestnik MGTU im. G.I. Nosova. 2016, no. 3, pp. 46–54. (In Russ.).

21. Krylov S.A., Makarov A.A., Tonysheva O.A., Mosolov A.N. Influence of consumable electrode quality on technological process of electroslag remelting under pressure of high-nitrogen steels. Elektronnyi nauchnyi zhurnal “Trudy VIAM”. 2018, no. 9 (69), pp. 3–10. (In Russ.).


Review

For citations:


Manashev I.R., Gavrilova T.O., Shatokhin I.M., Ziatdinov M.Kh., Leont’ev L.I. Utilization of dispersed waste of ferroalloy production on the basis of metallurgical SHS-process. Izvestiya. Ferrous Metallurgy. 2020;63(8):591-599. (In Russ.) https://doi.org/10.17073/0368-0797-2020-8-591-599

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ISSN 0368-0797 (Print)
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