Effect of additives introduction to fluxes manufactured from ladle electric steel slag
https://doi.org/10.17073/0368-0797-2019-8-606-612
Abstract
Studies of welding and surfacing fluxes containing ladle slag of electric-steel production of rail steel of JSC “EVRAZ ZSMK” were carried out. Welding under the flux was performed on the samples of sheet steel 09G2S by Sv-08GА wire using the weldingtractor ASAW1250 at exhaust modes. Chemical compositions of welding fluxes and slag crusts were determined. Also chemical composition of the studied welded samples was determined according to GOST 10543 – 98 by x-ray fluorescence method on XRF-1800 spectrometer and by atomic emission method on DFS-71 spectrometer. Metallographic studies were carried out with the use of an optical microscope OLYMPUS GX-51. The content of total oxygen and surface oxygen was studied using the LECO TC–600 analyzer. The possibility of using technogenic waste products of metallurgical production is shown for the production of welding fluxes. The following components were used for production of welding flux: ladle slag of electric steelmaking of rail steel from “EVRAZ ZSMK” JSC; BSK barium-strontium modifier produced under the terms of 1717-001-75073896 – 2005 by “NPK Metallotekhnoprom”; slag of silicomanganese production from “West Siberian steel plant”; electrostatic dust of aluminum production from “RUSAL” (carbonfluor-containing supplement). The studies have shown the suitability of the use of ladle electric steel slag for welding and surfacing of alloyed metal. The introduction of various flux additives reduces the concentration of total oxygen in the weld metal, which in turn increases the toughness. From the point of oxygen concentration in weld metal and impact toughness, it is better to use silica-manganese slag and carbon-fluoride additive as flux additives.
About the Authors
N. A. KozyrevRussian Federation
Dr. Sci. (Eng.), Professor, Head of the Chair “Materials, Foundry and Welding Production”
A. R. Mikhno
Russian Federation
MA Student of the Chair “Materials, Foundry and Welding Production”
R. E. Kryukov
Russian Federation
Cand. Sci. (Eng.), Assist. Professor of the Chair “Materials, Foundry and Welding Production”
A. N. Kalinogorskii
Russian Federation
Cand. Sci. (Eng.), Acting Head of the Chair of Ferrous Metallurgy
L. P. Bashchenko
Russian Federation
Cand. Sci. (Eng.), Senior Lecturer of the Chair “Thermal Power and Ecology”
References
1. Gulyaev A.P. Metallovedenie. Uchebnik dlya vuzov [Metal science. Textbook for universities]. Moscow: Metallurgiya, 1986, 544 p. (In Russ.).
2. Povolotskii D.Ya., Roshchin V.E., Mal’kov N.V. Elektrometallurgiya stali i ferrosplavov: uchebnik dlya vuzov [Electrometallurgy of steel and ferroalloys: Textbook for universities]. Moscow: Metallurgiya, 1995, 592 p. (In Russ.).
3. Titarenko V.I., Golyakevich A.A., Orlov L.N., Mosypan V.V., Babenko M.A., Telyuk D.V., Tarasenko V.V. Restoration surfacing of rolling mills rolls with flux-cored wire. Svarochnoe proizvodstvo. 2013, no. 7, pp. 29–32. (In Russ.).
4. Kondratiev I.A., Ryabtsev I.A. Flux-cored wires for surfacing of steel rollers for hot rolling. The Paton Welding Journal. 2014, no. 6, pp. 95–96.
5. Crespo A.C., Puchol R.Q., Goncalez L.P. etc. Obtaining a submerged arc welding flux of the MnO-SiO2-CaO-Al2O3-CaF2 system by fusion. Welding International. 2007, vol. 21, no. 7, pp. 502–511.
6. Naumov S.V., Kanina A.E., Ignatova A.M., Ignatov M.N. On fractional composition of welding fluxes. Nauchnotekhnicheskii vestnik Povolzh’ya. 2012, no. 2, pp. 126–169. (In Russ.).
7. Golovko V.V., Potapov N.N. Special features of agglomerated (ceramic) fluxes in welding. Welding International. 2011, vol. 25, no. 11, pp. 889–893.
8. Ogarkov N.N., Belyaev A.I. Stoikost’ i kachestvo prokatnykh valkov [Durability and quality of mill rolls]. Magnitogorsk: izd. MGTU, 2008, 131 p. (In Russ.).
9. Volobuev Yu.S., Surkov A.V., Volobuev O.S. etc. The development and properties of a new ceramic flux used for reconditioning rolling stock components. Welding International. 2010, vol. 24, no. 4, pp. 298–300.
10. Rybin V.V., Kalinnikov V.T., Brusnitsyn Yu.D. etc. High-quality components of welding materials from minerals of the Kolsky Peninsula and mining wastes. In: Nauchnye osnovy khimii i tekhnologii pererabotki kompleksnogo syr’ya i sinteza na ego osnove funktsional’nykh materialov. Materialy nauchnotekhnicheskoi konferentsii. T. 1 [Scientific fundamentals of chemistry and processing technology of complex raw materials and synthesis of functional materials on its basis. Materials of the Sci. and Tech. Conf. Vol. 1]. Apatity: Izd-vo Kol’skogo nauchnogo tsentra RAN, 2008, pp. 22–23. (In Russ.).
11. Bublik O.V., Chamov S.V. Advantages and shortcomings of ceramic (agglomerated) fluxes in comparison with fused fluxes used for the same applications. Welding International. 2010, vol. 24, no. 9, pp. 730–733.
12. Parshin S.G. Using ultrafine particles of activating fluxes for increasing the productivity of MIG/MAG welding of steels. Welding International. 2012, vol. 26, no. 10, pp. 800–804.
13. Shebanits E.N., Omel’yanenko N.I., Kurakin Yu.N., Matvienko V.N. Leshchinskii L.K., Dubinskii B.E., Stepnov K.K. Improving the fracture toughness and wear resistance of hard-faced hotrolling-mill rolls. Metallurgist. 2012, vol. 56, no. 7-8, pp. 613–617.
14. Volobuev Yu.S., Volobuev O.S., Parkhomenko A.G., Dobrozhela E.I., Klimenchuk O.S. Using a new general-purpose ceramic flux SFM-101 in welding of beams. Welding International. 2012, vol. 26, no. 8, pp. 649–653.
15. Pavlov I.V., Oleinichenko K.A. Regulating generation of CO by varying the composition of ceramic fluxes. Welding International. 1995, vol. 9, no. 4, pp. 329–332.
16. Kazakov Yu.V., Koryagin K.B., Potekhin V.P. Effect of activating fluxes on penetration in welding steels thicker than 8 mm. Welding International. 1991, vol. 5, no. 3, pp. 202–205.
17. Gur’ev S.V., Pletnev Yu.M., Murav’ev I.I. Investigation of the properties of welded joints produced by welding in a gas mixture and under a flux. Welding International. 2012, vol. 26, no. 8, pp. 646–648.
18. Potapov N.N., Feklistov S.I., Volobuev Yu.S., Potekhin V.P. A method of selecting fused fluxes in welding pearlitic-ferritic steel. Welding International. 2009, vol. 23, no. 10, pp. 800–803.
19. Kozyrev N.A., Kryukov R.E., Umanskii A.A., Mikhno A.R., Dumova L.V. Investigation and development of welding fluxes with the use of ladle electric-furnace slag and barium-strontium modifier for rolls surfacing. Izvestiya. Ferrous Metallurgy. 2018, vol. 61, no. 4, pp. 274–279. (In Russ.).
20. Kozyrev N.A., Kryukov R.E. Effective use of silicomanganese slag in welding fluxes production. In: Innovatsii v toplivnoenergeticheskom komplekse i mashinostroenii: sbornik trudov mezhdunarodnoi nauchnoprakticheskoi konferentsii, 1821 aprelya 2017 g. [Innovations in fuel and energy complex and engineering: Proceedings of Int. Sci.-Pract. Conf., April 18-21, 2017]. Kemerovo: KuzGTU, 2017, pp. 133–139. (In Russ.).
21. Kislov A.I., Mikhno A.R., Kozyrev N.A. Investigation of welding fluxes on the basis of silicomanganese slag and ladle electric steel slag. In: Nauka i molodezh’: problemy, poiski, resheniya: trudy uchnoi konferentsii studentov, aspirantov i molodykh uchenykh, 13-15 iyunya 2018 g. Vyp. 22. Ch. 2: Estestvennyei tekhnicheskie nauki [Science and youth: problems, searches, solutions: Papers of All-Russ. Sci. Conf. of Students, Graduate Students and Young Scientists, June 13-15, 2018. Vol. 22. Part 2: Natural and Technical Sciences]. Novokuznetsk: Izd. tsentr SibGIU, 2018, pp. 208–210. (In Russ.).
Review
For citations:
Kozyrev N.A., Mikhno A.R., Kryukov R.E., Kalinogorskii A.N., Bashchenko L.P. Effect of additives introduction to fluxes manufactured from ladle electric steel slag. Izvestiya. Ferrous Metallurgy. 2019;62(8):606-612. (In Russ.) https://doi.org/10.17073/0368-0797-2019-8-606-612