blackmetИзвестия высших учебных заведений. Черная МеталлургияIzvestiya. Ferrous Metallurgy0368-07972410-2091National University of Science and Technology "MISIS"10.17073/0368-0797-2022-10-683-692blackmet-2411Research ArticleМАТЕРИАЛОВЕДЕНИЕMATERIAL SCIENCEПокрытия из высокоэнтропийных сплавов: состояние проблемы и перспективы развитияCoatings from high-entropy alloys: State and prospectshttps://orcid.org/0000-0002-5147-5343ГромовВ. Е.GromovV. E.

Виктор Евгеньевич Громов, д.ф.-м.н., профессор, заведующий кафедрой естественнонаучных дисциплин им. профессора В.М. Финкеля

Россия, 654007, Кемеровская обл. – Кузбасс, Новокузнецк, ул. Кирова, 42

Viktor E. Gromov, Dr. Sci. (Phys.-Math.), Prof., Head of the Chair of Science named after V.M. Finkel’

42 Kirova Str., Novokuznetsk, Kemerovo Region – Kuzbass 654007, Russian Federation

gromov@physics.sibsiu.ruhttps://orcid.org/0000-0003-4809-8660КоноваловС. В.KonovalovS. V.

Сергей Валерьевич Коновалов, д.т.н., профессор, проректор по научной и инновационной деятельности

Россия, 654007, Кемеровская обл. – Кузбасс, Новокузнецк, ул. Кирова, 42

Sergei V. Konovalov, Dr. Sci. (Eng.), Prof., Vice-Rector for Research and Innovation

42 Kirova Str., Novokuznetsk, Kemerovo Region – Kuzbass 654007, Russian Federation

ksv@ssau.ruhttps://orcid.org/0000-0001-5154-5498ПерегудовО. А.PeregudovO. A.

Олег Александрович Перегудов, к.т.н., помощник ректора по молодежной политике

Россия, 644050, Омск, пр. Мира, 11

Oleg A. Peregudov, Cand. Sci. (Eng.), Rector’s Assistant for Youth Policy

11 Mira Ave., Omsk 644050, Russian Federation

olegomgtu@mail.ruhttps://orcid.org/0000-0002-4890-3730ЕфимовМ. О.EfimovM. O.

Михаил Олегович Ефимов, аспирант кафедры естественно­научных дисциплин им. профессора В.М. Финкеля

Россия, 654007, Кемеровская обл. – Кузбасс, Новокузнецк, ул. Кирова, 42

Mikhail O. Efimov, Postgraduate of the Chair of Science named after V.M. Finkel’

42 Kirova Str., Novokuznetsk, Kemerovo Region – Kuzbass 654007, Russian Federation

moefimov@mail.ruhttps://orcid.org/0000-0001-5677-1427ШляроваЮ. А.ShlyarovaYu. A.

Юлия Андреевна Шлярова, аспирант кафедры естественно­научных дисциплин им. профессора В.М. Финкеля

Россия, 654007, Кемеровская обл. – Кузбасс, Новокузнецк, ул. Кирова, 42

Yuliya A. Shlyarova, Postgraduate of the Chair of Science named after V.M. Finkel’

42 Kirova Str., Novokuznetsk, Kemerovo Region – Kuzbass 654007, Russian Federation

rubannikova96@mail.ruСибирский государственный индустриальный университетРоссияSiberian State Industrial UniversityRussian FederationОмский государственный технический университетРоссияOmsk State Technical UniversityRussian Federation2022301020226510683692Copyright © Громов В.Е., Коновалов С.В., Перегудов О.А., Ефимов М.О., Шлярова Ю.А., 20222022Громов В.Е., Коновалов С.В., Перегудов О.А., Ефимов М.О., Шлярова Ю.А.Gromov V.E., Konovalov S.V., Peregudov O.A., Efimov M.O., Shlyarova Y.A.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://fermet.misis.ru/jour/article/view/2411

Авторы выполнили краткий обзор публикаций зарубежных и отечественных исследований за последние годы, в которых изучаются структуры, фазовые составы и свойства пленок и покрытий пятикомпонентных высокоэнтропийных сплавов (ВЭС) на различные подложки и модифицирование поверхностей ВЭС различными видами обработки. В работе рассматриваются основные методы нанесения пленок и покрытий: магнетронное напыление, термическое распыление, лазерное напыление и электроосаждение. Особое внимание исследователи уделяют нанесению покрытий на нержавеющие стали и титановые сплавы. Положительное изменение трибологических, прочностных свойств и коррозионной стойкости пленочных покрытий проявляется в широком интервале температур. Обсуждаются возможные причины наблюдаемых эффектов с учетом роли твердорастворного упрочнения, формирования мелкозернистой структуры, образования оксидных слоев, обогащенных одним из компонентов ВЭС. Выделены новые способы нанесения покрытий из ВЭС и последующей обработки. Роль ниобия и титана в увеличении микротвердости, износостойкости и снижении коэффициента трения в покрытиях рассматривается на примере легирования этими элементами. Среди методов обработки поверхности ВЭС применяют электролитическое полирование, электроэрозионную обработку, механическую полировку и их комбинации. В ряде работ для повышения поверхностной прочности и износостойкости ВЭС предлагается использовать методику порошкового борирования. Проанализированы работы по одному из перспективных и продемонстрировавших высокую эффективность методов поверхностного упрочнения ВЭС – электронно-пучковой обработке.

The authors made a brief review of recent publications by foreign and domestic researchers on the structure, phase composition, and properties of films and coatings of five-component high-entropy alloys (HEA) on various substrates and modification of the HEA surface by various types of processing. The main methods of applying films and coatings are considered: magnetron sputtering, thermal sputtering, laser sputtering, and electrodeposition. Particular attention is paid to the deposition of coatings on stainless steels and titanium alloys. The positive change in the tribological, strength properties, and corrosion resistance of film coatings in a wide temperature range is analyzed and possible causes of the observed effects are discussed. The role of solid solution strengthening, formation of fine-grained structure, and the formation of oxide layers enriched with one of the HEA components were taken into account. The authors identified new methods for applying coatings from HEA and subsequent processing. Using Nb and Ti doping as an example, their role in increasing microhardness, wear resistance, and reducing the friction coefficient in coatings were revealed. Electrolytic polishing, electroerosive machining, mechanical polishing and their combination are considered among the methods of HEA surface treatment. A number of works propose a method of powder borating to increase the surface strength and wear resistance of HEAs. The paper considers analysis of works on electron-beam processing as one of the promising and high efficient methods of HEA surface hardening.

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The authors declare that there are no conflicts of interest present.